The semi-transparent photovoltaic (STPV) module is an emerging technology to harness the solar energy in the building. Nowadays, buildings are turning from energy consumers to energy producers due to the integration of the STPV module on the building envelopes and facades. In this research, the STPV module was integrated on the rooftop window of the experimental room at Kovilpatti (9°10′0″ N, 77°52′0″ E), Tamil Nadu, India. The performance of the STPV modules varies with respect to the geographical location, incident solar radiation, and surface temperature of the module. The surface temperature of the STPV module was regulated by the introduction of the mixture of graphene oxide and sodium sulphate decahydrate (Na2SO4·10H2O). The various concentration of the graphene oxide was mixed together with the Na2SO4·10H2O to enhance the thermal conductivity. The thermal conductivity of the mixture 0.3 concentration was found to be optimum from the analysis. The instantaneous peak temperature of the semi-transparent photovoltaic phase change material (STPV-PCM) module was reduced to 9 °C during summer compared to the reference STPV. At the same time, the energy conversion efficiency was increased by up to 9.4% compared to the conventional STPV module. Due to the incorporation of the graphene oxide and Na2SO4·10H2O, the daily output power production of the STPV module was improved by 12.16%.
In this work, the experimental investigations were piloted to study the influence of hybrid nanoparticles containing SiO2 and CeO2 nanoparticles on thermo-physical characteristics of the paraffin-based phase change material (PCM). Initially, the hybrid nanoparticles were prepared by blending equal mass of SiO2 and CeO2 nanoparticles. The hybrid-nano/paraffin (HnP) samples were prepared by cautiously dispersing 0, 0.5, 1.0, and 2.0 percentage mass of hybrid nanoparticles inside the paraffin, respectively. The synthesized samples were examined under different instruments such as field emission scanning electron microscope (FESEM), Fourier transform infrared spectrometer (FTIR), differential scanning calorimetry (DSC), thermogravimetric analyzer (TGA), and thermal properties analyzer to ascertain the influence of hybrid nanoparticles on thermo-physical characteristics of the prepared samples. The obtained experimental results proved that the hybrid nanoparticles were uniformly diffused in the paraffin matrix without affecting the chemical arrangement of paraffin molecules. Prominently, the relative thermal stability and relative thermal conductivity of the paraffin were synergistically enriched up to 115.49% and 165.56%, respectively, when dispersing hybrid nanoparticles within paraffin. Furthermore, the hybrid nanoparticles appropriately amended the melting and crystallization point of the paraffin to reduce its supercooling, and the maximum reduction in supercooling was ascertained as 35.81%. The comprehensive studies indicated that the paraffin diffused with SiO2 and CeO2 hybrid nanoparticles at 1.0 mass percentage would yield a better outcome compared to the next higher mass fractions without much diminishing the latent heat of paraffin. Hence, it is recommended to utilize the hybrid-nano/paraffin with 1.0 mass fraction of the aforementioned hybrid nanoparticles for effectively augmenting the thermal energy capacity of low-temperature solar thermal systems.
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