Silicone rubbers have advantageous thermal and electrical properties compared with other elastomers. Their mechanical properties, such as tensile strength and tear resistance are relatively weak compared with other elastomers. In this work, inorganic fillers such as titanium dioxide (TiO 2 ) 2 and 5 phr, quartz, aluminium silicate and vulkasil (s type) 5, 15 and 25 phr were used in silicone rubber compound samples. Improvement in mechanical and processing properties are observed for these samples. The samples containing 2 phr TiO 2 had a better tensile strength and transparency compared with those containing 5 phr TiO 2 . Determination of tensile strength, elongation at break, modulus, tear resistance, resilience and compression set of aged and unaged samples showed that higher values are obtained for samples containing quartz.
For industrial applications of engineering polymers such as polyurethane, polyamides and polyesters, the addition of suitable reinforcing inorganic fillers is a practical and convenient method to achieve the desirable mechanical and chemical properties. In this study, the mechanical, chemical and morphological properties of cast polyurethane samples containing barium sulphate, calcium carbonate, kaolin and quartz fillers were investigated. In the formulation of these samples, the ranges of inorganic filler were 0-40 phr. The results of mechanical property tests, such as tear resistance, tensile strength, elongation at break, Young's modulus, hardness and abrasion resistance, were evaluated. The chemical resistance of the samples was determined against xylene and methyl ethyl ketone. The chemical resistance of the filled cast polyurethane was determined by the solubility parameters of polymer/solvent. Finally, the experimental results and SEM images showed that samples containing 30 phr calcium carbonate produced the best results.
In this work, a new elastomeric liner was introduced to protect the metal surfaces of storage tanks against corroding materials in petrochemical industries. This new liner was prepared on the basis of EPDM/NR and EPDM/SBR compounds. The elastomeric compounds were cured by using super-heated water vapor at atmospheric pressure. To increase the rate of curing in these rubber samples, the optimum curing system contained 15 phr sulfur and 1.5 phr mercaptobenzothiazole, 1.5 phr zinc diethyl dithiocarbamate, and 1.8 phr tetramethylthiuram disulfide accelerators. Mechanical tests showed that ultimate tensile strength, elongation at break, and hardness of both polyblend samples were comparable to the SBR/NR blend, which is widely used in the rubber lining of metallic surfaces. In the next step, the chemical resistance of the samples was measured by placing them in a 30 wt % HCl solution. The tensile strength, elongation at break, and weight loss of the samples were measured before and after immersion in HCl. Also, the chemical resistances for EPDM/NR, EPDM/SBR, and SBR/NR samples were qualitatively measured in caustic solution. The cracking, blistering, permeability, and adhesion of the rubber samples to steel surface were observed. Finally, the results showed that EPDM/SBR (70/30) polyblend can be a suitable substitute for conventionally used SBR/NR (50/50) for a successful rubber used to line metallic surfaces.
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