A method was developed for measuring the capillary forces arising from microscopic pendular liquid bridges. Results are described for perfectly wetting bridges between spheres of equal and unequal radii. A comparison with the theoretical values calculated from a numerical integration of the Laplace-Young equation demonstrated the accuracy of the method. It also showed that existing criteria for gravitational distortion are too restrictive and that the influence of the disjoining pressure is negligible. The Derjaguin approximation for spheres of unequal size was shown to be relatively accurate for small bridge volumes and for separation distances excluding those at close-contact and near-rupture, which correspond to maxima in the filling angle. Closed-form approximations were developed in order to conveniently calculate the capillary forces between equal and unequal spheres as a function of the separation distance and for a given bridge volume and contact angle. A closed-form approximation was also developed to calculate the rupture distance for liquid bridges between spheres of unequal sizes.
The in vivo friction of human skin has been measured in the dry, wet and damp states using smooth glass and polypropylene spherically tipped probes. They were selected to be representative of hydrophilic and hydrophobic countersurfaces. The data are interpreted using the adhesion model of friction, which provides an explanation for the influence of the normal load and the surface free energies of the probe materials on the frictional characteristics of the skin. In particular, explanations based on this model are given for the tendency of wet skin to exhibit stick-slip motion and of damp skin to exhibit a peak frictional force against a glass probe.
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