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This study presents limnological and morphological characteristics, physical and chemical properties of waters, and geochemistry of surface sediments for 63 aquatic ecosystems located on the karst Yucatán Peninsula and surrounding areas of Belize and the Guatemalan highlands and eastern lowlands. Our principal goal was to classify the aquatic systems based on their water variables. A principal component analysis (PCA) of the surface water chemistry data showed that a large fraction of the variance (29%) in water chemistry is explained by conductivity and major ion concentrations. The broad conductivity range, from 168 to 55,300 lS cm -1 reflects saline water intrusion affecting coastal aquatic environments, and the steep NW-S precipitation gradient, from *450 to [3,200 mm year -1 . Coastal waterbodies Celestún and Laguna Rosada displayed the highest conductivities. Minimum surface water temperatures of 21.6°C were measured in highland lakes, and warmest temperatures, up to 31.7°C, were recorded in the lowland waterbodies. Most lakes showed thermal stratification during the sampling period, with the exception of some shallow (\10 m) systems. Lakes Chichancanab, Milagros, and Bacalar displayed sulfate-rich waters. Waters of sinkholes had relatively high conductivities (\3,670 lS cm -1 ) and a broad range of d 18 O values (-4.1 to ?3.8%). Ca, HCO 3 , and SO 4 dominated the waters of the lowland lakes, whereas Na was the dominant cation in highland lakes. Coastal aquatic ecosystems were dominated by Na and Cl. Cluster analysis based on surface water variables classified aquatic environments of the lowlands and highlands into three groups: (1) lowland lakes, ponds, wetlands, and coastal waterbodies (2) highland lakes, and (3) sinkholes and rivers. A broad trophic state gradient was recorded, ranging from the eutrophic Lake Amatitlán and the Timul sinkhole to oligotrophic Laguna Ayarza, with the highest water transparency (11.4 m). We used major and trace Handling editor: J.M. Melack

Lake Petén Itzá, northern Guatemala, lies within a hydrologically closed basin in the south-central area of the Yucatán Peninsula, and was drilled under the auspices of the International Continental Scientific Drilling Program (ICDP) in 2006. At 16°55′N latitude, the lake is ideally located for study of past climate and environmental conditions in the Neotropical lowlands. Because of its great depth (>160 m), Lake Petén Itzá has a record of continuous sediment accumulation that extends well into the late Pleistocene. A key obstacle to obtaining long climate records from the region is the difficulty of establishing a robust chronology beyond ∼40 ka, the limit of 14C dating. Tephra layers within the Lake Petén Itzá sediments, however, enable development of age/depth relations beyond 40 ka. Ash beds from large-magnitude, Pleistocene-to-Holocene silicic eruptions of caldera volcanoes along the Central American Volcanic Arc (CAVA) were found throughout drill cores collected from Lake Petén Itzá. These ash beds were used to establish a robust chronology extending back 400 ka. We used major- and trace-element glass composition to establish 12 well-constrained correlations between the lacustrine tephra layers in Lake Petén Itzá sediments and dated deposits at the CAVA source volcanoes, and with their marine equivalents in eastern Pacific Ocean sediments. The data also enabled revision of eight previous determinations of erupted volumes and masses, and initial estimates for another four eruptions, as well as the designation of source areas for 14 previously unknown eruptions. The new and revised sedimentation rates for the older sediment successions identify the interglacial of MIS5a between 84 and 72 ka, followed by a stadial between 72 and 59 ka that corresponds to MIS4. We modified the age models for the Lake Petén Itzá sediment sequences, extended the paleoclimate and paleoecological record for this Neotropical region to ∼400 ka, and determined the magnitude and timing of CAVA eruptions

Environmental reconstructions based on fossil pollen rely on the understanding of modern pollen distribution along climatic and biogeographic gradients. This study analyses the modern pollen spectra of Central America using three basic approaches: (1) the evaluation of using modern pollen spectra to differentiate the main vegetation types of the region, (2) the usage of non-linear regression to predict individual pollen abundances as a function of climate, and (3) the construction of pollen—climate transfer functions. Standard pollen analysis was carried out on mud—water interface samples from 81 lakes in the Yucatan Peninsula and adjacent mountains of Guatemala and Mexico. Detrended correspondence and cluster analyses were used to evaluate the biogeographic patterns revealed by this modern pollen data set. Non-parametric locally weighted scatterplot smoothing (LOESS) regression was used to construct pollen—climate functional relationships. Five modern vegetation types were clearly identifiable through their associated pollen spectra: Pinus forest, Quercus forest, mountain mesophyllous forest, tropical rainforest, and tropical seasonal forest. The last group includes three subcategories (evergreen seasonal, tropical semi-deciduous, and tropical deciduous forests), which were not separable via this analysis. Precipitation and temperature trends were consistent and robust for at least 28 and 30 taxa, respectively, in the LOESS regression. While floristic patterns driven by temperature were clearly reflected by the pollen spectra, those driven by precipitation were less sharply defined. Nevertheless, pollen data from the study area offered good resolution to identify broad biogeographic patterns. Furthermore, individual taxa showed high predictability along precipitation and temperature gradients, allowing the theoretical construction of pollen—climate transfer functions. This study provided valuable tools for the interpretation of fossil pollen sequences from Central America.

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