We report an improved synthesis of colloidal gold nanorods (NRs) by using aromatic additives that reduce the concentration of hexadecyltrimethylammonium bromide surfactant to ~0.05 M as opposed to 0.1 M in well-established protocols. The method optimizes the synthesis for each of the 11 additives studied, allowing a rich array of monodisperse gold NRs with longitudinal surface plasmon resonance tunable from 627 to 1246 nm to be generated. The gold NRs form large-area ordered assemblies upon slow evaporation of NR solution, exhibiting liquid crystalline ordering and several distinct local packing motifs that are dependent upon the NR's aspect ratio. Tailored synthesis of gold NRs with simultaneous improvements in monodispersity and dimensional tunability through rational introduction of additives will not only help to better understand the mechanism of seed-mediated growth of gold NRs but also advance the research on plasmonic metamaterials incorporating anisotropic metal nanostructures.

Monodisperse 3.1 nm Ag2Te NCs show a sharp optical absorption feature at 1154 nm with a large linear temperature dependence and the photoconductive response consistent with semiconducting character in Ag2Te NCs. The wavelength of the resonance is within the window of transparency for biological tissue making it a potential in vivo temperature marker or transducer for in situ heating with deep-penetrating near-infrared radiation.

Bismuth ferrite (BiFeO3) has recently become interesting as a room‐temperature multiferroic material, and a variety of prototype devices have been designed based on its thin films. A low‐cost and simple processing technique for large‐area and high‐quality BiFeO3 thin films that is compatible with current semiconductor technologies is therefore urgently needed. Development of BiFeO3 thin films is summarized with a specific focus on the chemical solution route. By a systematic analysis of the recent progress in chemical‐route‐derived BiFeO3 thin films, the challenges of these films are highlighted. An all‐solution chemical‐solution deposition (AS‐CSD) for BiFeO3 thin films with different orientation epitaxial on various oxide bottom electrodes is introduced and a comprehensive study of the growth, structure, and ferroelectric properties of these films is provided. A facile low‐cost route to prepare large‐area high‐quality epitaxial BFO thin films with a comprehensive understanding of the film thickness, stoichiometry, crystal orientation, ferroelectric properties, and bottom electrode effects on evolutions of microstructures is provided. This work paves the way for the fabrication of devices based on BiFeO3 thin films.