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A novel nonfullerene small molecular acceptor (BZIC) based on a ladder-type thieno[3,2-b]pyrrolo-fused pentacyclic benzotriazole core (dithieno[3,2-b]pyrrolobenzotriazole, BZTP) and end-capped with 1,1-dicyanomethylene-3-indanone (INCN) has been first reported in this work. Through introducing multifused benzotriazole and INCN, BZIC could maintain a high-lying lowest unoccupied molecular orbital (LUMO) energy level of -3.88 eV. Moreover, BZIC shows a low optical bandgap of 1.45 eV with broad and efficient absorption band from 600 to 850 nm due to increased π-π interactions by the covalently locking thiophene and benzotriazole units. A power conversion efficiency of 6.30% is delivered using BZIC as nonfullerene acceptor and our recently synthesized hexafluoroquinoxaline-based polymer HFQx-T as donor. This is the first time to synthesize mutifused benzotriazole-based molecules as nonfullerene electron acceptor up to date. The preliminary results demonstrate that the mutifused benzotriazole derivatives hold great potential for efficient photovoltaics.

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Flat-plate boundary layer transition induced by the wake vortex of a two-dimensional circular cylinder is experimentally investigated. Combined visualization and velocity measurements show a different transition route from the Klebanoff mode in free-stream turbulence-induced transition. This transition scenario is mainly characterized as: (i) generation of secondary transverse vortical structures near the flat plate surface in response to the von Kármán vortex street of the cylinder; (ii) formation of hairpin vortices due to the secondary instability of secondary vortical structures; (iii) growth of hairpins which is accelerated by wake-vortex induction; (iv) formation of hairpin packets and the associated streaky structures. Detailed investigation shows that during transition the evolution dynamics and self-sustaining mechanisms of hairpins, hairpin packets and streaks are consistent with those in a turbulent boundary layer. The wake vortex mainly plays the role of generating and destabilizing secondary transverse vortices. After that, the internal mechanisms become dominant and lead to the setting up of a self-sustained turbulent boundary layer.

The flow over a circular cylinder controlled by a two-dimensional synthetic jet positioned at the mean rear stagnation point has been experimentally investigated in a water channel at the cylinder Reynolds number Re = 950. This is an innovative arrangement and the particle-image-velocimetry measurement indicates that it can lead to a novel and interesting phenomenon. The synthetic-jet vortex pairs induced near the exit convect downstream and interact with the vorticity shear layers behind both sides of the cylinder, resulting in the formation of new induced wake vortices. The present vortex synchronization occurs when the excitation frequency of the synthetic jet is between 1.67 and 5.00 times the natural shedding frequency at the dimensionless stroke length 99.5. However, it is suggested that the strength of the synthetic-jet vortex pair plays a more essential role in the occurrence of vortex synchronization than the excitation frequency. In addition, the wake-vortex shedding is converted into a symmetric mode from its original antisymmetric mode. The symmetric shedding mode weakens the interaction between the upper and lower wake vortices, resulting in a decrease in the turbulent kinetic energy produced by them. It also has a significant influence on the global flow field, including the velocity fluctuations, Reynolds stresses and flow topology. However, their distributions are still dominated by the large-scale coherent structures.