This study focuses in the synthesis of ceramic pigments based on the crystal structure of willemite (Zn2SiO4). The willemite obtained from the combination of commercial zinc oxide and rice husk ash is produced in a conventional ceramic process without the use of mineralizer agent and with the addition of cobalt oxide or nickel oxide as the source of chromophore ions. The synthesis temperature used was 1200°C. The characterization of pigments involves the use of X-ray diffraction and scanning electron microscopy. The pigments applied in matte enamel and sintered at 1100°C or 1200°C developed color between blue and beige. The construction of absorbance curves showed the color development behavior of each pigment. The results showed the possibility of obtaining willemite, from rice husk ash and the color development efficiency of the material, besides showing the interference of chromophore ion (Ni and Co) in color development.
The effluents from carbonization or pyrolysis and wood charcoal have aggregated thermal energy and, in conventional charcoal kilns, part of the wood is burned to ignite the burning in the kilns and the effluents generated are dispensed in the atmosphere and in the soil, which causes energy losses and environmental pollution. In this study we seek a clean and sustainable alternative to produce energy, in addition to the search for a system with satisfactory performance in the generation of electric energy. The objective of this study was to evaluate how much electricity can be produced from wood carbonization effluents by ONDATEC technology, using the Brayton and Rankine cycle, also known as Combined Cycle. This method presents a high power generation efficiency, around 50%, compared to other generation systems. A field experiment was carried out from October 21st to 24th, 2010 to determine the calorific value of wood carbonization effluents, using a microwave oven, (condensable and non-condensable gas), in the city of Uberaba -Mg, Brazil. The data generated in this study reveals important information for companies looking for a way to produce clean and renewable electricity from reforestation wood, in addition to the effort to minimize environmental pollution, ensure sustainability in production systems and the growing search for new sources of energy. A complete description of the experiment, including details of the project, is presented in this work.
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