Graphitic carbon nitride (g-CN) behaving as a layered feature with graphite was indexed as a high-content nitrogen-doping carbon material, attracting increasing attention for application in energy storage devices. However, poor conductivity and resulting serious irreversible capacity loss were pronounced for g-CN material due to its high nitrogen content. In this work, magnesiothermic denitriding technology is demonstrated to reduce the nitrogen content of g-CN (especially graphitic nitrogen) for enhanced lithium storage properties as lithium ion battery anodes. The obtained nitrogen-deficient g-CN (ND-g-CN) exhibits a thinner and more porous structure composed of an abundance of relatively low nitrogen doping wrinkled graphene nanosheets. A highly reversible lithium storage capacity of 2753 mAh/g was obtained after the 300th cycle with an enhanced cycling stability and rate capability. The presented nitrogen-deficient g-CN with outstanding electrochemical performances may unambiguously promote the application of g-CN materials in energy-storage devices.
The modulation of TiO 2 structure can effectively alter the oxidation kinetics and pathway of sacrificial ethanol during the water-splitting reaction and dramatically adjust the selectivity of the valuable coupling product 2,3-butanediol from 0.0% to 96.6%, showing the possibility of photohydrogen production in green and economical indexes.Light-driven water splitting to produce hydrogen has drawn great attention due to increasing global concerns on fossil energy resources and climate problems. 1,2 Since the electrochemical photolysis of water on a titanium oxide (TiO 2 ) electrode was first discovered by Fujishima and Honda, 3 great progress has been achieved in understanding the microscopic processes involved in the photochemical systems 4-6 and catalysts, 7-10 and in the modulation of catalyst structures for visible light harvesting. 11-13 However, light-driven hydrogen production still faces many challenging issues for practical application.Light-driven water splitting intrinsically undergoes two reaction moieties: the reduction of protons (H + ) to molecular hydrogen by photo-excited electrons, and the oxidation of water to dioxygen by holes. 14 In an ideal photocatalytic system for permanent high-rate hydrogen generation, the oxidation half-reaction should match well with the reduction half-reaction; however, in most cases, it proceeds at a considerably low rate and greatly limits the total photocatalytic oxidation-reduction cycle. Sacrificial reductants, such as methanol and ethanol, are normally required to speed up hole consumption and slow down electron-hole recombination, 15,16 which can dramatically enhance hydrogen evolution by several orders of magnitude. 17 However, the use of sacrificial reductants undesirably brings along several problems, such as: (1) the water-splitting reaction is actually changed into a redox reaction between water and the sacrificial reductants, greatly increasing the system cost; and (2) sacrificial alcohols are normally converted to CO 2 and other oxidation products, 18,19 causing the photocatalytic H 2 O-to-H 2 energy-storage process to lose its intrinsic clean, non-carbon feature. These problems seriously influence the progress and realization of solar hydrogen production. Great efforts have been made to develop new catalysts for H 2 -O 2 co-generation, so that sacrificial reductants become unnecessary. 7,[20][21][22][23][24] This strategy seems ideal for the H 2 O-to-H 2 process, but the achievement of efficient, highly stable, and low-cost catalysts appears to require further research. Additionally, the H 2 -O 2 mixture produced may suffer from engineering difficulties in terms of
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.