Reaction in a scalar mixing layer in grid-generated turbulence is studied experimentally by doping half of the flow with nitric oxide and the other half with ozone. The flow conditions and concentrations are such that the chemical reaction is passive and the flow and chemical timescales are of the same order. Conserved scalar theory for such flows is outlined and further developed; it is used as a basis for presentation of the experimental results. Continuous measurements of concentration are limited in their spatial and temporal resolution but capture sufficient of their spectra for adequate second-order correlations to be made. Two components of velocity have been measured simultaneously with hot-wire anemometry. Conserved scalar mixing results, deduced from reacting and non-reacting measurements of concentration, show the independence of concentration level and concentration ratio expected for passive reacting flow. The results are subject to several limitations due to the necessary experimental compromises, but they agree generally with measurements made in thermal mixing layers. Reactive scalar statistics are consistent with the realizability constraints obtainable from conserved scalar theory where such constraints apply, and otherwise are generally found to lie between the conserved scalar theory limits for frozen and very fast chemistry. It is suggested that Toor's (1969) closure for the mean chemical reaction rate could be improved by interpolating between the frozen and equilibrium values for the covariance. The turbulent fluxes of the reactive scalars are found to approximately obey the gradient model but the value of the diffusivity is found to depend on the Damköhler number.

This investigation was designed to (a) develop an individualized mechanical model for measuring aerodynamic drag (F(d) ) while ski racing through multiple gates, (b) estimate energy dissipation (E(d) ) caused by F(d) and compare this to the total energy loss (E(t) ), and (c) investigate the relative contribution of E(d) /E(t) to performance during giant slalom skiing (GS). Nine elite skiers were monitored in different positions and with different wind velocities in a wind tunnel, as well as during GS and straight downhill skiing employing a Global Navigation Satellite System. On the basis of the wind tunnel measurements, a linear regression model of drag coefficient multiplied by cross-sectional area as a function of shoulder height was established for each skier (r > 0.94, all P < 0.001). Skiing velocity, F(d) , E(t) , and E(d) per GS turn were 15-21 m/s, 20-60 N, -11 to -5 kJ, and -2.3 to -0.5 kJ, respectively. E(d) /E(t) ranged from ∼5% to 28% and the relationship between E(t) /v(in) and E(d) was r = -0.12 (all NS). In conclusion, (a) F(d) during alpine skiing was calculated by mechanical modeling, (b) E(d) made a relatively small contribution to E(t) , and (c) higher relative E(d) was correlated to better performance in elite GS skiers, suggesting that reducing ski-snow friction can improve this performance.

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