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The low-and high-temperature structures of La2CoMnO6 and
La2NiMnO6
have been refined using powder neutron diffraction. At low temperatures the
materials adopt a charge-ordered monoclinic structure which transforms to a
rhombohedral structure at elevated temperature without loss of charge ordering.
This charge ordering scheme allows us for the first time to rationalize the
relationships between the physical and structural properties of these materials.
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