Chiral N-heterocyclic carbenes, which are derived from C2-symmetric 1,3-bis(1-arylethyl)imidazolium salts, catalyze enantioselective acylation of racemic secondary alcohols.
Enantioselective syntheses O 0031First Example of Chiral N-Heterocyclic Carbenes as Catalysts for Kinetic Resolution. -Chiral N-heterocyclic carbenes, which are derived from C2-symmetric 1,3-bis(1-arylethyl)imidazolium salts (I), catalyze the enantioselective acylation of racemic secondary alcohols. -(SUZUKI*, Y.; YAMAUCHI, K.; MURAMATSU, K.; SATO, M.; Chem.
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