We propose a method to experimentally determine the Clausius–Mossotti factors and surface capacitances of colloidal particles. This two-step method is based on the following: (i) a precise positioning of particles on activated electrodes according to the applied frequency of an electric field and (ii) particles velocities measurements from a pure dielectrophoretic regime to build the Clausius–Mossotti factor. It confirms previous literature methods and measures the surface capacitance values for a wide range of particles such as polystyrene, silica, and gold whose diameters are at least 200 nm.

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