The molecular structure of the title complex, [Ni2(C11H13NO3)2]·CH3OH, contains two NiII atoms and two doubly deprotonated 6-methoxy-2-{[(3-oxidopropyl)imino]methyl}phenolate ligands. The NiII atoms are each four-coordinated in a distorted square-planar geometry by three O atoms and one N atom derived from the phenolate ligands. The solvent molecule is linked to the complex molecule by two O—H⋯O hydrogen bonds.
C 27 H 20 FN 3 S 2 Sn, monoclinic, P2 1 /n (no. 14), a = 15.631 (4)
CCDC no.: 1580160The crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.
Source of materialsThe ligand: 5-((4-fluorobenzylidene)amino)thiophene-2-thiol was synthesized by 4-fluorobenzaldehyde and 5-aminothiophene-2-thiol by refluxing in ethanol for 2 h (yellow solid). The organic ligand and triphenyltin chloride were added to benzene and sodium ethoxide, refluxed for
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