Confining light in extremely small cavities is crucial in nanophotonics, central to many applications. Employing a unique nanoparticle-on-mirror plasmonic structure and using a graphene film as a spacer, we create nanoscale cavities with volumes of only a few tens of cubic nanometers. The ultracompact cavity produces extremely strong optical near-fields, which facilitate the formation of single carbon quantum dots in the cavity and simultaneously empower the strong coupling between the excitons of the formed carbon quantum dot and the localized surface plasmons. This is manifested in the optical scattering spectra, showing a magnificent Rabi splitting of up to 200 meV under ambient conditions. In addition, we demonstrate that the strong coupling is tuneable with light irradiation. This opens new paradigms for investigating the fundamental light emission properties of carbon quantum dots in the quantum regime and paves the way for many significant applications.

This study aimed to evaluate the improvement in strength and durability of the bond between dentin and composite resins following plasma drying of the etched dentin surface using non‐thermal atmospheric pressure plasma. Plasma drying was applied to the etched dentin before applying adhesive. Conventional wet‐bonding and helium (He) gas‐dried bonding schemes were used as control groups. The bond strength of the composite resin to dentin was measured as the microtensile bond strength at 24 h after bonding and after 10,000 cycles of thermocycling. Hybrid layer formation was observed using micro‐Raman spectroscopy and scanning electron microscopy. Although the bond‐strength values were not statistically different either at 24 h after bonding or after thermocycling, the bond strength of the plasma‐dried bonding group was significantly higher than the conventional wet‐bonding group and He gas‐dried bonding group. Micro‐Raman spectral analysis revealed effective penetration of the adhesive and an improved polymerization rate of the adhesive after plasma drying. Plasma drying increased the penetration of hydrophobic resin into the collagen mesh structure, which improved mechanical bonding and long‐term durability between dentin and composite resin.

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