Most of the nutrients in municipal wastewater originate from urine. Nevertheless, chemical fertilizers are commonly used in the agriculture instead of urine. There are some problems related to the direct utilization of urine, such as micropollutants present in urine, odour and storage of large volume of urine. In wastewater, phosphorus may contribute significantly to the pollution of the aquatic systems. Therefore, wastewater treatment techniques are mainly focusing on removing phosphorus. Phosphorus is collected in the sludge either by a chemical or by a biological process. With the growing concern of micropollutants present, which are in the sludge, the use of sludge in agriculture has been gradually decreasing. It means that the phosphorus content in sludge is not recycled efficiently whereas the use of limited mineral phosphorus resources is growing. To overcome these issues, urine could be collected separately and struvite could be produced. This may recover about 90 % of phosphate in urine. In this paper, the use of human urine and struvite as a fertilizer in the agriculture and the production of struvite is discussed. Results showed that the struvite could be an effective natural fertilizer.
In agriculture, the human urine could have been used as a natural fertilizer, although there are some problems with the direct utilization, such as the presence of micropollutants in urine, odour and storage of large volume of urine. Therefore, nutrients, such as nitrogen, can be recovered from urine. Continuous flow laboratory membrane reactor was built to investigate nitrogen recovery from wastewater and from human urine. Membrane gas separation method has not been investigated for ammonia recovery from human urine yet. Nitrogen as ammonia gas was recovered in acid using Zeus Aeos™ ePTFE gaspermeable hydrophobic membrane. Acid flux, operating pH, hydraulic retention time and effective membrane surface were experimentally determined. The aim of this work was to verify wastewater experiments in professional flowsheet environment, rigorously modelled with ChemCAD and optimized by dynamic programming optimization method: the membrane separation. Such nitrogen recovery membrane separation has not been published in this professional flowsheet environment yet. The objective function of the process is the ammonia harvesting efficiency. Eighty-five percentage ammonia harvesting efficiency can be reached with 60 membrane surface area/reactor volume ratio, at 35 °C feed temperature with 350 L/m 2 h acid and in 8 h' hydraulic retention time. It can be stated that this separation method is based on physical phenomena without any biological factors. The focus for nitrogen treatment in a wastewater treatment plant is removal instead of recovery. It can be determined that this system is capable for the nitrogen recovery from wastewater, and it can reduce the ammonia content of human urine too.
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