. Can. J. Chem. 59,2096Chem. 59, (1981. Deamination of 2-amino-4,4-dideuterio-6,6-dimethylcyclohexanone, 2-exo-amino-and 2-endo-amino-norbornane-3-one, 2-diazonorbornan-3-one, 2-exo-amino-5,6-exo-dideuterionorbornan-3-one and the corresponding 5,6-endo-dideuterio isomer has been studied. The nature of the products, the deuterium location in them, and the high retention of steric identity in the carbocations are interpreted in terms of o-bond participation leading to corner-and edge-protonated cyclopropanes as reaction intermediates. Results with other destabilized carbocations are correlated.OLIVER E. EDWARDS, JOHN DIXON, JOHN W. ELDER, RALPH J. KOLT et MAURICE LESAGE. Can. J. Chem. 59,2096 (1981. On a etudik la desamination de I'amino-2 dideutero-4,4 dimethyl-6,6 cyclohexanone, des amino-2 exo et amino-2 endo norbornanones-3, de la diaza-2 norbornanone-3, de l'amino-2-exo dideutero-5,6-exo norbornanone-3, ainsi que de son isomkre dideutero-5,6-endo. On interprete la nature des produits, la position des deuterium qu'ils contiennent ainsi que le taux eleve de retention [Traduit par le journal]
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.