A three‐dimensional conductive nanocomposite with an ordered conductive network and low percolation threshold has been successfully prepared by blending graphite nanosheets (GNs) with polyethylene on a two‐roll mill. The conductive nanosheets orient intensively in the composite, leading to highly anisotropic properties. The nanocomposite with the fraction of conductive nanosheets closest to the percolation threshold possesses a sharp positive pressure coefficient of resistivity, in which the abrupt transition can be attributed to compressive‐stress‐induced deformation of the conductive network. Such piezoresistive effects depend strongly on filler morphology, filler spatial arrangement, and filler concentration.
Metal-organic frameworks (MOFs) are a new type of functional material that is self-assembled by metal ions and organic ligands. In this paper, a bimetal-organic framework was synthesized and stripped into two-dimensional nanosheets structure via an ultrasonic method. We coated the UMOFNs (ultrathinning MOFs into two-dimensional nanosheets) on AgPO nanoparticles to obtain AgPO@UMOFNs core-shell photocatalysts. Under visible-light irradiation, the degradation of phenol was 100% within 16 min, and the degradation of biphenyl A was 98.9% within 20 min via AgPO@UMOFNs (5 wt %). These values were 1.6- and 1.8-times higher than AgPO, respectively. The activity of the AgPO@UMOFNs increased due to the synergistic effects. The π-π bonds of the organic ligands and weak interactions between UMOFNs and AgPO collectively promote charge transfer. In addition, matching energy-level structures and a sufficiently large contact area accelerate the separation of the photogenerated charges and improve the activity. This remarkably improves the photocatalytic activity.
A novel functional tweezer based on uracil-appended glycyrrhetinic acid with excellent gelation ability was synthesized, and the gel could transform to sol by F(-) and Hg(2+).
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