The great harm of thiram residue in soil to environment and human health is usually ignored. Due to the complexity of soil compositions, the detection of thiram residue in soil faces considerable difficulties. In this work, a highly sensitive and selective surface-enhanced Raman scattering (SERS) substrate based on the triangular silver nanoplates (TSNPs) with small size and sharp corners is developed and used for the detection of thiram residue in soil for the first time. These TSNPs are synthesized by replacing the conventional seeds in the seed-mediated chemical reduction route with the tiny and uniform triangular silver nuclei (TSN) which can provide more growing space for generating sharp corners during the growth of TSNPs. It is interesting that the TSNPs with the smaller size have the better SERS performance. The possible mechanism behind this phenomenon is explained by the electromagnetic enhancement theory. On the basis of the Raman activity of the smallest TSNPs, a SERS-active substrate is prepared for detecting the thiram residue in soil. The thiram solution detection shows that the limit of detection (LOD) of these smallest TSNPs is lower than other nanoparticles, such as nanospheres, nanocubes, etc. For sensing the thiram residue in soil, the addition of poly(sodium 4-styrenesulfonate) realizes the specific adsorption of thiram by TSNPs. This method exhibits a good linear response from 0.12 to 4.8 μg/g with a low LOD of 90 ng/g, which is better than conventional methods. This work shows the great potential of the small TSNPs as a novel SERS substrate and its broader applications in pesticides detection.
The interface chemistry and evolution of the evaporated perovskite films on ITO, pedot/ITO, Si and glass substrates are studied. As evidenced by X-ray diffraction and X-ray photoemission spectroscopy (XPS) results, the PbI2 phase is found to be inevitably formed at the very initial growth stage, even under the conditions of a MAI-rich environment. The extremely low binding energy of adsorbed MAI particles on all the above substrates, as compared to that of PbI2 particles, is responsible for the presence of the PbI2 phase at the interface. The formation of both hole and electron barriers at the interface of PbI2/MAPbI3, as evidenced by XPS measurements, could block carrier transport into the electrode and thus deteriorate solar cell performance. This result reveals the origin of the poor performance of perovskite solar cells (PSCs) by the vacuum evaporation method, and may help to improve the performance of PSCs made using the vacuum evaporation method.
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