Physical interactions often occur between major food components during food processing. These interactions may involve starch, lipids, and proteins forming V-type starch-lipid complexes or ternary starch-lipid-protein complexes of larger molecular size and greater structural order. Complexes between starch and lipids have been the subject of intensive research for over half a century, whereas the study of starchlipid-protein complexes is a relatively new field with only a limited amount of knowledge being gained so far. The formation of these complexes can significantly affect the functional and nutritional properties of finished food products in terms of flavor, texture, shelf life, and digestibility. This article provides a comprehensive review of starch-lipid and starch-lipid-protein complexes, including their classification, factors affecting their formation and structure, and preparative and analytical methods. The review also considers how complexes affect the physicochemical and functional properties of starch, including digestibility, and potential applications in the food industry.
K E Y W O R D Sapplications, digestibility, multi-scale structure, preparative methods, starch-lipid complex, starch-lipidprotein complex 1056
The
aim of the present study was to investigate the interactions
between maize starch (MS), β-lactoglobulin (βLG), and
monoglycerides (MG) containing different fatty acids in a model system.
Results from the Rapid Visco Analyzer (RVA) showed that MS–MGC14:0 and MS–MGC16:0 systems presented a
viscosity peak during the RVA cooling and/or holding stage, while
MS–MGC18:0, MS–MGC18:1, and MS–MGC18:2 systems did not show obvious changes in the pasting profile.
Addition of βLG altered significantly the pasting profiles of
MS–MG systems in different ways, with the most obvious change
observed for the MS–MGC18:0 system. Results from
differential scanning calorimetry (DSC), Raman spectroscopy, and X-ray
diffraction showed that the complexes in ternary systems were more
ordered than those in binary systems. The thermal transition temperatures
of complexes in binary and ternary systems were similar, although
the enthalpy changes were greater for ternary than for binary systems.
From the above results, we concluded that addition of βLG promoted
the formation of MS–MG complexes rather than the involvement
of formation of ternary MS–MG−βLG complexes.
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