In heterogeneous polymers and emulsions, the volume fraction of the discrete phase and the frequency of electromagnetic waves affect the accuracy of the dielectric model. The integral method was used to modify the Maxwell–Wagner (M–W) heterogeneous dielectric theory, and a new model for the complex dielectric constant of polymers and emulsions was established. The experimental data were compared with the results of the M–W heterogeneous dielectric integral modification model and other theoretical models for different frequencies and volume fractions of the discrete phase. We discovered that with a decreasing volume fraction of the discrete phase, the dominant frequency range of the integral modification model expanded. When the volume fraction of the discrete phase is 10%, the dominant frequency range reaches 3 GHz. When the volume fraction of the discrete phase is 1%, the dominant frequency range reaches 4 GHz. When the volume fraction of the discrete phase is 0.06%, the dominant frequency range of the real part reaches 9.6 GHz, and the dominant frequency range of the imaginary part reaches 7.2 GHz. These results verify the advantages of the M–W modification model, which provides a theoretical basis to study the dielectric properties of polymers and emulsions, as well as for microwave measurement.
Coupling energy storage system is one of the potential ways to improve the peak regulation and frequency modulation performance for the existing combined heat power plant. Based on the characteristics of energy storage types, achieving the accurate parameter design for multiple energy storage has been a necessary step to coordinate regulation. In this work, heat storage tank for peak regulation and flywheel energy storage for frequency modulation have been carried out, including the parameters design and performance evaluation for their the charging (or discharging) rate and capacity, and the collaborative optimization of dual energy storage systems has been realized. First, the effects of increasing peak depth, load change rate (frequency modulation) range and energy storage parameters are further analyzed. It is worth noting that the power curves of regional thermal and electrical loads would be adjusted according to the set requirements. Results showed that, the set rate of charge and discharge as well as the capacity of energy storage are conducive to improving the peak regulation depth of the system, and the peak regulation depth would reach its limit at 96.35MW and 40.83MWh in the calculation cases, respectively. On this basis, the cooperative regulation of dual energy storage can further increase the capability of peak regulation and frequency modulation. The extreme point is that when the charge and discharge rates are both 3MW, and meanwhile the peak clipping coefficient, a self-defined parameter, reaches 22.34MW. Furthermore, an example calculation is carried out to verify the reliability of the design method of energy storage parameter. The specific parameters set include the charging and discharging rate of energy storage tank equipment is 61.67MW, and its capacity is 10.64MWh, and the charging and discharging rate of flywheel energy storage equipment is 3MW. The example results confirmed that there was only a very small error between the set results and the calculation results. Finally, the thermal-electric load region has been drawn to contrast the key roles of dual energy storage systems, which indicates that the heat storage tank can be used for peak regulation and flywheel energy storage for frequency modulation. Overall, the parameter design method for dual energy storage can meet the engineering requirements and provide a new direction for the subsequent parameter design of thermal power unit coupled energy storage system.
Solid waste has interactions with its flue-gas products during combustion, which offers the possibility of regulating its pollutant emissions. Especially, these interaction pathways would be clearer under anaerobic conditions when the chemical-looping combustion (CLC) process is used. The CLC experiments of multi-component solid waste were conducted on a homemade twin-bed reactor and the characteristics of flue gas were investigated for the effect of the mixing ratio of sewage sludge and polyvinyl chloride (PVC). The results indicated that the combustion efficiency was >99.9% for these CLC processes; the highest carbon-conversion rate was obtained at 96.3% for PVC with 60% sludge. The highest NO and SO2 emissions were 26% and 19%, respectively, when the sludge was mixed with 20% PVC. As the proportion of PVC blended into the sludge increased, the time when the concentration of NO in the flue-gas peaks moved backwards, while peak SO2 concentration moved forward. The general trend was to increase first and then decrease. In addition, there were multiple peaks in carbon emissions, corresponding to ~10%, 30% and ~70% of the carbon-conversion rate; nitrogen emissions reached 90% of total emissions before the carbon-conversion rate was 40%; sulphur emissions had a longer cycle and were mainly emitted between 10% and 60% of the carbon-conversion rate. The results are expected to provide a reference for solid-waste source suppressing to inhibit the generation of pollutants.
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