Independent and zero-maintenance systems would be in urgent need in the near future internet of things. Here, we present highperformance, self-driven organic/inorganic heterojunction ultraviolet (UV) photodetectors (PDs) by in situ polymerization of polyaniline (PANI) on Gallium nitride microwires. The GaN microwires with a high crystalline quality are grown on patterned Si substrates by metal organic chemical vapor deposition. Using a facile in situ chemical polymerization method, PANI is conformally coated on the surface of GaN microwires. The constructed GaN/PANI hybrid microwire PD exhibits a high responsivity of 178 mA/W, a remarkable detectivity of 4.67 × 10 14 jones, and an ultrafast UV photoresponse speed (rise time of 0.2 ms and fall time of 0.3 ms) under zero bias. The intimate heterojunction in the form of N−Ga−N bonds between GaN and PANI may account for the observed high performances. The presented self-driven microwire UV PDs featuring ultrahigh-speed (sub-millisecond) response to UV light may find applications in future nano/micro-photosensor networks.
Many constitutive models are available nowadays to predict soil-structure interaction problems. It is sometimes not very easier for engineers to select a suitable soil model to carry out their design analyses in terms of complexity versus accuracy. This paper describes the application of three constitutive models to back-analyse a well-instrumented centrifuge model test, in which the effect of basement excavation on an existing tunnel was simulated. These three models include a linear elastic-perfectly plastic model with the Mohr-Coulomb failure criterion (called MC model), a nonlinear elastic Duncan-Chang model (DC) and a hypoplastic model (HP), the last of which can capture path-dependent and strain-dependent soil stiffness even at small strains. By comparing with measured data from the centrifuge model test, it is found that the HP model yielded the best predictions of tunnel heave among the three models. Not only the gradient but also the magnitude of tunnel heave is predicted well by this HP model. This can be explained by the fact that the HP model can capture the path-dependent and strain-dependent soil stiffness even at small strains but not the MC and DC models. However, all three models underestimated the change in tunnel diameter and the maximum tensile bending strain in the transverse direction.
Photoelectrochemical (PEC) water splitting has great application potential in converting solar energy into hydrogen energy. However, what stands in the way of the practical application of this technology is the low conversion efficiency, which can be promoted by optimizing the material structure and device design for surface functionalization. In this work, we deposited gold nanoparticles (Au NPs) with different loading densities on the surface of InGaN nanorod (NR) arrays through a chemical solvent route to obtain a composite PEC water splitting system. Enhanced photocatalytic activity, which can be demonstrated by the surface plasmon resonance (SPR) effect induced by Au NPs, occurred and was further confirmed to be associated with the different loading densities of Au NPs. These discoveries use solar water splitting as a platform and provide ideas for exploring the mechanism of SPR enhancement.
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