In the present research work the degradation of acid yellow 17 (AY 17) by H2O2/Fe2+ was investigated. The effect of various conditions such as pH value, temperature, conc. of H2O2, Fe2+, conc. of AY 17 were studied. Additionally the scavenging effects of various anions such as Cl−, SO42−, CO32− and HCO3−, on percent degradation of AY 17 were examined. It was found that these anions decrease percent degradation as well as rate of degradation reaction. The optimum conditions were determined as [AY 17]=[Fe2+]=0.06 mM [H2O2]=0.9 mM, and pH 3.0 for 60 min of reaction time. It was found that at optimum conditions 89% degradation of AY17 was achieved. The degradation kinetics of AY17 followed pseudo-first-order reaction kinetics. Thermodynamic studies under natural conditions showed positive value of ∆H (enthalpy) which indicates the degradation process is endothermic.
We report here the degradation of AY-17 dye using Fenton-like process (H2O2/Fe 3+ ). The maximum degradation (83%) of AY17 dye is achieved at pH 3 in 60 min, with optimum concentrations of AY 17 (0.06 mM), H2O2 (0.9 mM), and Fe 2+ (0.06 mM). The scavenging effects of HCO3 − , CO3 2− , Cl − and SO4 2− on dye degradation are also examined. The activation energy (Ea), activation enthalpy (H * ), and activation entropy (S * ) are calculated for the dye degradation using pseudo-first-order kinetics at various temperature.
In the present study, we have synthesized conducting polymer nanocomposites consist of silver nanoparticles (AgNPs), graphene, and polyvinyl acetate (PVAc) emulsion. The synthesized nanocomposite was characterized by UV/Vis, FT-IR, XRD, TGA, and SEM techniques. SEM images showed that AgNPs and graphene sheets are well dispersed in the PVAc matrix. The electrical conductivities of the nanocomposites were examined using the impedance analyzer instrument. It was ascertained that polymer composite containing silver nanoparticles and graphene exhibit higher conductivities. The PVAc-AgNPs/Graphene nanocomposite was also used as potential conducting materials for humidity measurement.
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