[1] During an earthquake, the heat generated by fault friction may be large enough to activate the devolatilization of minerals forming the fault rocks. In this paper, we model the mechanical effects of calcite thermal decomposition on the slip behavior of a fault zone during an earthquake. To do so, we introduce the coupled effects of calcite volume loss, heat consumption, and CO 2 production in the theoretical analysis of shear heating and thermal pressurization of pore fluids. We consider a rapidly deforming shear band consisting of a fluid-saturated carbonate rock. The equations that govern the evolution of pore pressure and temperature inside the band and the mass of emitted CO 2 are deduced from the mass and energy balance of the multiphase-saturated medium and from the kinetics of the chemical decomposition of calcite. Numerical simulation of seismic slip at depths of 5 to 8 km show that decarbonation has two critical consequences on fault slip. First, the endothermic reaction of calcite decomposition limits the coseismic temperature increase to less than $800°C (corresponding to the initiation of the chemical reaction) inside the shear band. Second, the rapid emission of CO 2 by decarbonation significantly increases the slip-weakening effect of thermal pressurization. The pore pressure reaches a maximum and then decreases due to the reduction of solid volume, causing a restrengthening of shear stress. Our theoretical study shows, on the example of decarbonation, that the thermal decomposition of minerals is an important slip-weakening process and that a large part of the frictional heat of earthquakes may go into endothermic devolatilization reactions.Citation: Sulem, J., and V. Famin (2009), Thermal decomposition of carbonates in fault zones: Slip-weakening and temperaturelimiting effects,
The effective stress law for the permeability of a limestone is studied experimentally by performing constant head permeability tests in a triaxial cell with different conditions of confining pressure and pore pressure. Test results have shown that a pore pressure increase and a confining pressure decrease both result in an increase of the permeability, and that the effect of the pore pressure change on the variation of the permeability is more important than the effect of a change of the confining pressure. A power law is proposed for the variation of the permeability with the effective stress. The permeability effective stress coefficient increases linearly with the differential pressure and is greater than one as soon the differential pressure exceeds few bars. The test results are well reproduced using the proposed permeability-effective stress law. A conceptual pore-shell model based on a detailed observation of the microstructure of the studied limestone is proposed. This model is able to explain the experimental observations on the effect of the total stress and of the pore pressure on the permeability of the limestone. Effective stress coefficients for the stress-dependent permeability which are greater than one are obtained. It is shown that the controlling factor is the ratio of the different bulk moduli of the various constituents of the rock. This ratio is studied experimentally by performing microhardness tests.Comment: International Journal of Rock Mechanics and Mining Sciences (2008) In pres
Temperature increase in saturated porous materials under undrained conditions leads to thermal pressurization of the pore fluid due to the discrepancy between the thermal expansion coefficients of the pore fluid and of the solid matrix. This increase in the pore fluid pressure induces a reduction of the effective mean stress and can lead to shear failure or hydraulic fracturing. The equations governing the phenomenon of thermal pressurization are presented and this phenomenon is studied experimentally for a saturated granular rock in an undrained heating test under constant isotropic stress. Careful analysis of the effect of mechanical and thermal deformation of the drainage and pressure measurement system is performed and a correction of the measured pore pressure is introduced. The test results are modelled using a non-linear thermo-poro-elastic constitutive model of the granular rock with emphasis on the stress-dependent character of the rock compressibility. The effects of stress and temperature on thermal pressurization observed in the tests are correctly reproduced by the model
International audienceThe poromechanical behaviour of hardened cement paste under isotropic loading is studied on the basis of an experimental testing program of drained, undrained and unjacketed compression tests. The macroscopic behaviour of the material is described in the framework of the mechanics of porous media. The poroelastic parameters of the material are determined and the effect of stress and pore pressure on them is evaluated. Appropriate effective stress laws which control the evolution of total volume, pore volume, solid volume, porosity and drained bulk modulus are discussed. A phenomenon of degradation of elastic properties is observed in the test results. The microscopic observations showed that this degradation is caused by the microcracking of the material under isotropic loading. The good compatibility and the consistency of the obtained poromechanical parameters demonstrate that the behaviour of the hardened cement paste can be indeed described within the framework of the theory of porous media
International audienceIn this paper, the mechanism of fault pressurization in rapid slip events is analysed on the basis of a complete characterization of the thermo-poro-mechanical behaviour of a clayey gouge extracted at 760 m depth in Aigion fault in the active seismic zone of the Gulf of Corinth, Greece. It is shown that the thermally collapsible character of this clayey gouge can be responsible for a dramatic reduction of effective stress and a full fluidization of the material. The thickness of the ‘ultra-localized’ zone of highly strained material is a key parameter that controls the competing phenomena of pore pressure increase leading to fluidization of the fault gouge and temperature increase leading to pore-fluid vapourization
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