The synthesis of composites thin films made by injecting an aerosol suspension of 20 nm‐size TiO2 nanoparticles (NPs) and isopropanol (IPA) in a filamentary argon Dielectric Barrier Discharge (DBD) is studied as a function of the DBD frequency from 1 to 50 kHz. The plasma is modulated to get homogeneous coatings. The deposition rate and morphology of the composite thin films are determined from SEM images of both surface and cross section. Their chemical composition is investigated by XPS, Raman spectroscopy and FTIR measurements. The structural composition of the NPs is examined by XRD. All the deposited composites show the chemical signature of the NPs as well as of the polymer‐like coating resulting from the plasma polymerization of IPA. No mixed phase is observed and the sizes of the NPs as well as of their aggregates are not affected by the plasma. With this method aerosol droplets are evaporated before entering the plasma and the NPs inside a same droplet are aggregated. Results show that the DBD frequency controls the composite composition by independently influencing the NPs transport and the matrix growth rate. At 1 kHz, the coating is essentially made of NPs with a low carbon coating. From 1 to 50 kHz, the Ti/C ratio is divided by two orders of magnitude. As the frequency increases the quantity of NPs decreases and since 10 kHz the matrix thickness increases. The decrease of the NPs is explained by the numerical modeling of the NPs trajectory. It is found that from 10 to 1 kHz, the lower is the frequency, the higher is the transport of the NPs to the surface due to the electrostatic force. On the other hand the matrix growth rate increases from almost zero at 10 kHz up to 19 nm · min−1 at 50 kHz because of the linear increases of the DBD power with the frequency.

The study of small reservoirs with low suspended sediment concentration (CSS) is still a challenge for remote sensing. In this work we estimate CSS from the optical properties of water and orbital imagery. Campaigns were carried out at selected dates according to the calendar of sensor passages, rainfall seasonality and hydrograph of the reservoir for the collection of surface water samples and field spectroradiometry. The calibration between CSS and spectral behavior generated CSS estimation models from MODIS and Landsat 8 data, allowing investigation of their temporal and spatial behavior. The MODIS model generated a time series of CSS from 2000 to 2017, presenting R2 = 0.8105 and RMSE% = 39.91%. The Landsat 8 model allowed the spatial analysis of CSS, with R2 = 0.8352 and RMSE% = 15.12%. The combination of the proposed models allowed the temporal and spatial analysis of the CSS and its relationships with the rainfall regime and the quota variation of the Descoberto reservoir (DF). The results showed that the use of orbital data complements the CSS information obtained by the traditional methods of collecting and analyzing water quality in low CSS reservoirs.

International audienceAtmospheric hypervelocity impacts are widely viewed to produce the meteoric smoke layer by the shock-less interactions of the impinging air molecules with the vaporized meteoroid. In contrast here, we intend to show how gas and solid aerosols when captured in the Mach cone of a bolide while entering the Earth atmosphere are transformed into a new range of polymeric nanomaterials. Carbonaceous materials from natural situations are studied from collect in a pilot region of Southern France in the following days of a high altitude meteor atmospheric airburst on 2011 August 2 nd and since the 2013 February 15 th Chelyabinsk meteoritic event in Ural. These materials are compared to the ones obtained by hypervelocity shock with the CEA Persephone light-gas gun. A numerical simulation with the Tycho software is performed to model the evolution of the increase of density directly in the rear front of the shockwave with the increase of velocity around an obstacle for high velocity inflow. The multidisciplinary approach reveals the production carbon-based nanosolids from terrestrial precursors by hypervelocity plasma particle deposition (HPPD) processes. The Tycho simulation helps to establish the lack of mixing between the ablation smoke and the surrounding atmosphere. The correlation between the simulation, the hypervelocity experiments and the natural situations shows the distinctive characteristics of visco-elastic filamentary nanosolids formed in the laminar domain of low pressure, the ones of nanoparticle-rich stiff film specific to the thin domain of high shear stress and the ones of dense glassy carbon with nanocarbon crystallites (graphite and graphene-like) only formed in the frontal high temperature and pressure domain. Data on the natural carbon-based nanosolids indicate that the atmospheric shock-dissociation occurred from a carbon pool dominated by dead atmospheric carbon. Diagnostic keys are provided to distinguish natural carbon-based nanosolids synthesized by HPPD just at the time of the hypervelocity atmospheric entry from their subsequent transformations during atmospheric transport by other aeroplasma processes

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