SrTiO 3. Whereas in oxygen-deficient SrTiO 3−x and Nb-doped SrTiO 3 films the Hall constant increases markedly below 100 K (29), it is less temperature dependent in LaAlO 3 /SrTiO 3 hetero-structures. In addition, the upper critical field of the heterostructures is an order of magnitude smaller than that of Nb-SrTiO 3 with the same T c. Finally, our observation of both superconducting and insulating behavior on the same sample, depending on the precise LaAlO 3 layer thickness, is very hard to reconcile with a pure oxygen vacancy scenario. Magnetic anisotropy allows magnets to maintain their direction of magnetization over time. Using a scanning tunneling microscope to observe spin excitations, we determined the orientation and strength of the anisotropies of individual iron and manganese atoms on a thin layer of copper nitride. The relative intensities of the inelastic tunneling processes are consistent with dipolar interactions, as seen for inelastic neutron scattering. First-principles calculations indicate that the magnetic atoms become incorporated into a polar covalent surface molecular network in the copper nitride. These structures, which provide atom-by-atom accessibility via local probes, have the potential for engineering anisotropies large enough to produce stable magnetization at low temperatures for a single atomic spin.