Organolead halide perovskites currently are the new front‐runners as light absorbers in hybrid solar cells, as they combine efficiencies passing already 20% with deposition temperatures below 100 °C and cheap solution‐based fabrication routes. Long‐term stability remains a major obstacle for application on an industrial scale. Here, it is demonstrated that significant decomposition effects already occur during annealing of a methylammonium lead triiode perovskite at 85 °C even in inert atmosphere thus violating international standards. The observed behavior supports the view of currently used perovskite materials as soft matter systems with low formation energies, thus representing a major bottleneck for their application, especially in countries with high average temperatures. This result can trigger a broader search for new perovskite families with improved thermal stability.
The increasing amount of research on solution-processable, organic donor-acceptor bulk heterojunction photovoltaic systems, based on blends of conjugated polymers and fullerenes has resulted in devices with an overall power-conversion efficiency of 6%. For the best devices, absorbed photon-to-electron quantum efficiencies approaching 100% have been shown. Besides the produced current, the overall efficiency depends critically on the generated photovoltage. Therefore, understanding and optimization of the open-circuit voltage (Voc) of organic solar cells is of high importance. Here, we demonstrate that charge-transfer absorption and emission are shown to be related to each other and Voc in accordance with the assumptions of the detailed balance and quasi-equilibrium theory. We underline the importance of the weak ground-state interaction between the polymer and the fullerene and we confirm that Voc is determined by the formation of these states. Our work further suggests alternative pathways to improve Voc of donor-acceptor devices.
The open-circuit voltage ͑V oc ͒ of polymer:fullerene bulk heterojunction solar cells is determined by the interfacial charge-transfer ͑CT͒ states between polymer and fullerene. Fourier-transform photocurrent spectroscopy and electroluminescence spectra of several polymer:fullerene blends are used to extract the relevant interfacial molecular parameters. An analytical expression linking these properties to V oc is deduced and shown to be valid for photovoltaic devices comprising three commonly used conjugated polymers blended with the fullerene derivative ͓6,6͔-phenyl-C61-butyric acid methyl ester ͑PCBM͒. V oc is proportional to the energy of the CT states E CT . The energetic loss q⌬V between E CT and qV oc vanishes when approaching 0 K. It depends linearly on T and logarithmically on illumination intensity. Furthermore q⌬V can be reduced by decreasing the electronic coupling between polymer and fullerene or by reducing the nonradiative recombination rate. For the investigated devices we find a loss q⌬V of ϳ0.6 eV at room temperature and under solar illumination conditions, of which ϳ0.25 eV is due to radiative recombination via the CT state and ϳ0.35 eV is due to nonradiative recombination.
Organometal halide perovskites have tremendous potential as light absorbers for photovoltaic applications. In this work we demonstrate hybrid solar cells based on the mixed perovskite CH3 NH3 PbI2 Cl in a thin film sandwich structure, with unprecedented reproducibility and generating efficiencies up to 10.8%. The successfulness of our approach is corroborated by the experimental electronic structure determination of this perovskite.
Photocurrent generation by charge-transfer (CT) absorption is detected in a range of conjugated polymer: [6,6]-phenyl C 61 butyric acid methyl ester (PCBM) based solar cells. The low intensity CT absorption bands are observed using a highly sensitive measurement of the external quantum efficiency (EQE) spectrum by means of Fourier-transform photocurrent spectroscopy (FTPS). The presence of these CT bands implies the formation of weak groundstate charge-transfer complexes in the studied polymer:fullerene blends. The effective band gap (E g ) of the material blends used in these photovoltaic devices is determined from the energetic onset of the photocurrent generated by CT absorption. It is shown that for all
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