Abstract. Goal of the project CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrumented Container) is to carry out regular and detailed observations of atmospheric composition (particles and gases) at cruising altitudes of passenger aircraft, i.e. at 9-12 km. Mercury has been measured since May 2005 by a modified Tekran instrument (Tekran Model 2537 A analyser, Tekran Inc., Toronto, Canada) during monthly intercontinental flights between Europe and South and North America, Africa, and Asia. Here we describe the instrument modifications, the post-flight processing of the raw instrument signal, and the fractionation experiments.

Abstract. The knowledge of the vertical distribution of atmospheric mercury (Hg) plays an important role in determining the transport and cycling of mercury. However, measurements of the vertical distribution are rare, because airborne measurements are expensive and labour intensive. Consequently, only a few vertical Hg profile measurements have been reported since the 1970s. Besides the Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container (CARIBIC) observations, the latest vertical profile over Europe was measured in 1996. Within the Global Mercury Observation System (GMOS) project, four vertical profiles were taken on board research aircraft (CASA-212) in August 2013 in background air over different locations in Slovenia and Germany. Each vertical profile consists of at least seven 5 min horizontal flight sections from 500 m above ground to 3000 m a.s.l. Gaseous elemental mercury (GEM) and total gaseous mercury (TGM) were measured with Tekran 2537X and Tekran 2537B analysers. In addition to the mercury measurements, SO2, CO, O3, NO, and NO2, basic meteorological parameters (pressure, temperature, relative humidity) have been measured. Additional ground-based mercury measurements at the GMOS master site in Waldhof, Germany and measurements onboard the CARIBIC passenger aircraft were used to extend the profile to the ground and upper troposphere respectively. No vertical gradient was found inside the well-mixed boundary layer (variation of less than 0.1 ng m−3) at different sites, with GEM varying from location to location between 1.4 and 1.6 ng m−3 (standard temperature and pressure, STP: T  =  273.15 K, p  =  1013.25 hPa). At all locations GEM dropped to 1.3 ng m−3 (STP) when entering the free troposphere and remained constant at higher altitudes. The combination of the vertical profile, measured on 21 August 2013 over Leipzig, Germany, with the CARIBIC measurements during ascent and descent to Frankfurt Airport, Germany, taken at approximately the same time, provide a unique central European vertical profile from inside the boundary layer (550 m a.s.l) to the upper free troposphere (10 500 m a.s.l.) and show a fairly constant free-tropospheric TGM concentration of 1.3 ng m−3 (STP).

Abstract. Goal of the project CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrumented Container) is to carry out regular and detailed observations of atmospheric composition (particles and gases) at cruising altitudes of passenger aircraft, i.e. at 9 – 12 km. Mercury has been measured since May 2005 by a modified Tekran instrument (Tekran-Analyzer Model 2537 A, Tekran Inc., Toronto, Canada) during monthly intercontinental flights between Europe and South and North America, Africa and Asia. Here we describe the instrument modifications, the post-flight processing of the raw Tekran signal, and the speciation experiments.

Marine radars are increasingly popular for monitoring meteorological and oceanographic parameters such as ocean surface wind, waves and currents as well as bathymetry and shorelines. Within this paper a coherent on receive marine radar is introduced, which is based on an incoherent off the shelf pulsed X-band radar. The main concept of the coherentization is based on the coherent on receive principle, where the coherence is achieved by measuring the phase of the transmitted pulse from a leak in the radar circulator, which then serves as a reference phase for the transmitted pulse. The Doppler shift frequency can be computed from two consecutive pulse-pairs in the time domain or from the first moment of the Doppler spectrum inferred by means of a short time Fast Fourier Transform. From the Doppler shift frequencies, radial speed maps of the backscatter of the ocean surface are retrieved. The resulting backscatter intensity and Doppler speed maps are presented for horizontal as well as vertical polarization, and discussed with respect to meteorological and oceanographic applications.

Abstract. Hg / SO 2 , Hg / CO, NO x / SO 2 (NO x being the sum of NO and NO 2 ) emission ratios (ERs) in the plume of the coal-fired power plant (CFPP), Lippendorf, near Leipzig, Germany, were determined within the European Tropospheric Mercury Experiment (ETMEP) aircraft campaign in August 2013. The gaseous oxidized mercury (GOM) fraction of mercury emissions was also assessed. Measured Hg / SO 2 and Hg / CO ERs were within the measurement uncertainties consistent with the ratios calculated from annual emissions in 2013 reported by the CFPP operator, while the NO x / SO 2 ER was somewhat lower. The GOM fraction of total mercury emissions, estimated using three independent methods, was below ∼ 25 %. This result is consistent with other findings and suggests that GOM fractions of ∼ 40 % of CFPP mercury emissions in current emission inventories are overestimated.