Efficient palladium catalyst systems consisting of bench-stable biaryl phosphacycles and Pd(OAc)2 are described for Suzuki–Miyaura cross-coupling reactions of a diverse array of aryl halides and arylboronic acids.

Electronic and steric properties of the newly developed biaryl phosphacycles were quantified from various experimental and theoretical methods. These include user-friendly and rapid packages such as Solid-G, SambVca, and FindConeAngle...

No abstract

No abstract