An assessment of high-temperature mass spectrometry and of sources of inaccuracy is made. Experimental, calculated, and estimated cross-sections for ionization of atoms and inorganic molecules typically present in high-temperature vapors are summarized. Experimental cross-sections determined for some 56 atoms are generally close to theoretically calculated values, especially when excitation–autoionization is taken into account. Absolute or relative cross-sections for formation of parent ions were measured for ca. 100 molecules. These include homonuclear diatomic and polyatomic molecules, oxides, chalcogenides, halides, and hydroxides. Additivity of atomic cross-sections supplemented by empirical corrections provides fair estimates of molecular cross-sections. Causes of uncertainty are differences in interatomic distances and in shapes of potential energy curves (surfaces) of neutral molecules and of molecular ions and tendency toward dissociative ionization in certain types of molecules. Various mass spectrometric procedures are described that render the accuracy of measured thermodynamic properties of materials largely independent of ionization cross-sections. This accuracy is comparable with that of other techniques applicable under the conditions of interest, but often only the mass spectrometric procedure is appropriate at high temperatures.
The role played by inorganic c he mi cal additives in fire retardancy and flam e inhibition is considered. Particular attention is given to the molec ular level aspects of co mm ercially important systems containing co mpound s of antimony, halogens, and phosphorus. The flam e inhibiting function of metal containing additives is also discussed.
A number of possible designs of external and in-vessel coils generating resonant magnetic perturbations (RMPs) for Type I edge localized modes (ELMs) control in ITER are analysed for the reference scenarios (H-mode, Hybrid and Steady-State) taking into account physical, technical and spatial constraints. The level of stochasticity (Chirikov parameter ∼1 at ψ1/2 ∼ 0.95) generated by the I-coils in the DIII-D experiments on ELMs suppression was taken as a reference. Designs with a toroidal symmetry n = 3 were considered to avoid lower n numbers producing larger central islands, a potential trigger of MHD instabilities. The evaluation of RMP coils designs is done with respect to the RMPs spectrum that should produce enough edge ergodisation and minimum central perturbations at minimum current. The proposed designs include in-vessel, mid-ports and external coils. Changes in the equilibrium due to changes in the internal inductance l
i, the poloidal beta βp and the edge magnetic shear in a reasonable range for ITER scenarios were demonstrated to have a small effect on the edge ergodisation. Present estimations were done without margins and for vacuum fields neglecting plasma response on RMPs. The validity of the vacuum approach was estimated analytically in the visco-resistive linear response regime using [1]. The typical radial magnetic field amplitudes produced by RMP coils in DIII-D and ITER are an order of magnitude or slightly above the critical values for the ‘downward’ bifurcation to the reconnected stage indicating the possibility of the islands formation in the pedestal region. Central islands (from the top of the pedestal) are expected to be screened.
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