Direct numerical simulations of fully developed turbulence in an open channel geometry were performed in which a passive scalar was introduced. The simulations were intended to explore transport at free surfaces in two cases for which (1) the free surface was maintained at constant temperature and (2) the interfacial flux was fixed. These cases can be considered models for mass and evaporative heat transport where buoyancy and surface deformation effects are negligible. Significant differences were found in the thermal fields in these two cases. The turbulent statistics reveal that the surface flux in the constant temperature case was significantly more intermittent compared to the surface temperature field in the constant flux case. The surface temperature field in the latter case formed large patches of warm fluid, reminiscent of the so-called fish scale patterns revealed in recent infrared imagery of the air–water interface. The wake-like structure of the patches was evident despite the absence of surface shear. A model of surface renewal based on the existence of two disparate time scales (a fast hydrodynamic scale, and a slow, diffusional scale) was introduced to explain these differences in a heuristic manner. The model appears successful in explaining, in a qualitative sense, the surface thermal structure in each case. Correlations between the surface thermal fields (flux or temperature) and the subsurface hydrodynamics were also computed. A model based on the hypothesis that hairpin eddies are the dominant kinematic structure responsible for surface renewal is consistent with the correlations. However, these results cannot rule out the importance of other turbulent structures in free surface heat and mass transport processes.
Objective:Survey of nicotine, tar, and carbon monoxide (CO) smoke deliveries from 77 cigarette brands purchased in 35 countries was conducted using a standardised machine smoking method. The goal of this study was to determine regional variations and differences in the tar, nicotine, and CO smoke yields of a cigarette brand manufactured by a leading transnational corporation and of non-US locally popular cigarette brands.Design:The majority of the cigarettes were purchased in each of the participating countries by delegate members of the World Health Organization and forwarded to the Centers for Disease Control and Prevention for analysis. Smoke deliveries were determined using a standardised smoking machine method and subsequent gravimetric and gas chromatography analysis.Results:The smoke deliveries varied widely. Mainstream smoke deliveries varied from 6.8 to 21.6 mg tar/cigarette, 0.5 to 1.6 mg nicotine/cigarette, and 5.9 to 17.4 mg CO/cigarette. In addition to the smoke deliveries, the cigarettes were examined to determine physical parameters such as filter composition, length, and ventilation levels.Conclusion:Analysis of the smoke deliveries suggested that cigarettes from the Eastern Mediterranean, Southeast Asia, and Western Pacific WHO regions tended to have higher tar, nicotine, and CO smoke deliveries than did brands from the European, American, or African WHO regions surveyed.
Mesler entrainment is the formation of large numbers of small bubbles which occurs when a drop strikes a liquid reservoir at a relatively low velocity. Existing studies of Mesler entrainment have focused almost exclusively on water as the working fluid in a nominally clean state, where even very small levels of contamination can cause significant changes in surface tension that affect the repeatability of the results. Herein water combined with the soluble surfactant Triton X-100 is used as the working fluid in an attempt to stabilize the state of the water surface. Despite this approach, nominally identical drops did not always result in the same bubble formation event. Accordingly, Mesler entrainment was quantified by its frequency of occurrence for drops having the same nominal diameter and impact velocity. This frequency of occurrence was found to be well correlated to both the Weber number and the shape of the drop on impact. V
Turbulence measurements are reported for the flow beneath an air/water interface undergoing evaporative convection. Measurements were obtained using a two component laser Doppler velocimeter system. Two hydrodynamic boundary conditions were considered for the free surface: a shear free surface, which is the case when surfactants are absent, and a constant elasticity surface, created by depositing a monolayer of oleyl alcohol. The shear free boundary condition case results in significantly higher levels of near surface turbulence than the constant elasticity case. This difference between the two cases decreases with distance from the free surface. Profiles of the turbulent fluctuations were obtained for the horizontal and vertical velocity components and are compared with the somewhat analogous case of a heated solid wall.
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