Laser-induced breakdown spectroscopy (LIBS) is a technique that provides an accurate in situ quantitative chemical analysis and, thanks to the developments in new spectral processing algorithms in the last decade, has achieved a promising performance as a quantitative chemical analyzer at the atomic level. These possibilities along with the fact that little or no sample preparation is necessary have expanded the application fields of LIBS. In this paper, we review the state of the art of this technique, its fundamentals, algorithms for quantitative analysis or sample classification, future challenges, and new application fields where LIBS can solve real problems.
The long interaction pathlengths provided by hollow-core photonic bandgap fibers (HC-PBFs) are especially advantageous for the detection of weakly absorbing gases such as methane (CH(4)). In this paper, we demonstrate methane sensing with a 1670-nm band HC-PBF. A multiline algorithm is used to fit the R(6) manifold (near 1645 nm) and, in this way, to measure the gas concentration. With this method, a minimum detectivity of 10 ppmv for the system configuration was estimated.
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