Buffering of high-pH (>12) steel slag leachate is documented across a small, natural calcareous wetland. The alkaline leachate is supersaturated with respect to calcite upstream of the wetland (Sl(calcite) values +2.3) and becomes less saturated with progress across the wetland, to Sl(calcite) values of +0.27 at the wetland outlet. Reduction in pH across the wetland (to around pH 8 at the wetland outlet) was observed to be more pronounced over summer months, possibly due to increased microbial activity, possibly further assisted by greater flow baffling by emergent vegetation. Calculated calcite precipitation rates downstream of the leachate source, estimated from hydrochemical data, flow, and surface area, were on the order of 0.4-15 g m(-2) day(-1), while direct measurements (using immersed limestone blocks) showed calcite precipitation values in the range 3-10 g m(-2) day(-1). Precipitation rate was highest in the pH range where the carbonate ion is a dominant constituent of sample alkalinity (pH 9.5-11) and at the locations where wetland biota became established downstream of the leachate emergence. These data provide valuable insights into the potential for using constructed wetlands for the passive treatment of high pH steel slag leachates.

Treatment of polluting discharges from abandoned coal mines in the UK currently produces ca 30,000 t y(-1) of hydrous iron oxides ("ochre"), for which there is no major end-use, but which has previously been shown to have potential for removing P from wastewater and agricultural runoff. The efficiency of ochre for P removal from wastewater was investigated in experiments at two sites in the UK: Leitholm in Scotland and Windlestone in England. The three-year experiment at Leitholm involved diverting secondary-treated wastewater effluent through a trough which contained granular and pelletized ochre at different times. In the nine-month experiment at Windlestone, beds of ochre pellets in horizontal and vertical flow configurations were tested. The ochre treatment systems at Leitholm reduced influent concentrations of total P (TP) and TP mass by ca 80% and 50%, respectively, during optimal flow conditions, and achieved a removal rate of up to 65+/-48 mg TP kg(-1) ochre d(-1). There was no detectable release of potentially toxic metals from the ochre during the experiments. P removal rates by concentration were inversely related to flow and declined during the different phases of the experiments, probably due to clogging. At Windlestone, higher removal rates up to 195 mg TP kg(-1) ochre d(-1) were achieved for short periods of time following cleaning of the experimental system. Ochre has considerable potential to remove P from wastewater in a multi-stage treatment system and has a lifetime estimated to be 10 times longer than other substrates tested for P removal.

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recent research has demonstrated considerable potential for artificial soils to be designed for carbon capture. The incorporation of quarry fines enables the accumulation of atmospheric cO 2 in newly formed carbonate minerals. However, the rate and trajectory of carbon accumulation has been little studied. The relative contribution of biotic (e.g. vegetation, micro-organisms) and abiotic (water, light, temperature) factors to the carbonation process is also unknown. This article presents a sustainability framework which aims to determine the multi-functionality of soils to which fines have been added not only in their role as carbon sinks but also in their role of providing additional opportunities for improvement to ecosystem services. Such frameworks are required specifically where land designed for cO 2 capture must also provide other ecosystem services, such as flood mitigation and biodiversity conservation. land within linear transport infrastructure provides a case study, focusing on 238,000 ha of vegetated land associated with roadside verges in the UK. Hypothetically this area could remove 2.5 t cO 2 per year from the atmosphere, equivalent to 1% 2011 total UK emissions or 2% of current transport emissions and saving an equivalent of £1.1 billion in non-traded mitigation values. roadside verges should be designed to minimize flooding onto the highway and perform other important functions such as removal of dust and suspended solids from surface waters. Vegetation on 30,000 ha of railway land also provides opportunities for carbon sequestration, but management of this vegetation is subject to similar constraints to protect the rail tracks from debris extending from autumn leaves to fallen trees.

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