Polyanion compounds offer a playground for designing prospective electrode active materials for sodium-ion storage due to their structural diversity and chemical variety. Here, by combining a NaVPO4F composition and KTiOPO4-type framework via a low-temperature (e.g., 190 °C) ion-exchange synthesis approach, we develop a high-capacity and high-voltage positive electrode active material. When tested in a coin cell configuration in combination with a Na metal negative electrode and a NaPF6-based non-aqueous electrolyte solution, this cathode active material enables a discharge capacity of 136 mAh g−1 at 14.3 mA g−1 with an average cell discharge voltage of about 4.0 V. Furthermore, a specific discharge capacity of 123 mAh g−1 at 5.7 A g−1 is also reported for the same cell configuration. Through ex situ and operando structural characterizations, we also demonstrate that the reversible Na-ion storage at the positive electrode occurs mostly via a solid-solution de/insertion mechanism.
Prussian blue analogues (PBAs) are commonly believed to reversibly insert divalent ions, such as calcium and magnesium, rendering them as perspective cathode materials for aqueous magnesium‐ion batteries. In this study, the occurrence of Mg2+ insertion into nanosized PBA materials is shown to be a misconception and conclusive evidence is provided for the unfeasibility of this process for both cation‐rich and cation‐poor nickel, iron, and copper hexacyanoferrates. Based on structural, electrochemical, IR spectroscopy, and quartz crystal microbalance data, the charge compensation of PBA redox can be attributed to protons rather than to divalent ions in aqueous Mg2+ solution. The reversible insertion of protons involves complex lattice water rearrangements, whereas the presence of Mg2+ ion and Mg salt anion stabilizes the proton (de)insertion reaction through local pH effects and anion adsorption at the PBA surface. The obtained results draw attention to the design of proton‐based batteries operating in environmentally benign aqueous solutions with low acidity.
The Prussian Blue analogue K2−δMn[Fe(CN)6]1−ɣ∙nH2O is regarded as a key candidate for potassium-ion battery positive electrode materials due to its high specific capacity and redox potential, easy scalability, and low cost. However, various intrinsic defects, such as water in the crystal lattice, can drastically affect electrochemical performance. In this work, we varied the water content in K2−δMn[Fe(CN)6]1−ɣ∙nH2O by using a vacuum/air drying procedure and investigated its effect on the crystal structure, chemical composition and electrochemical properties. The crystal structure of K2−δMn[Fe(CN)6]1−ɣ∙nH2O was, for the first time, Rietveld-refined, based on neutron powder diffraction data at 10 and 300 K, suggesting a new structural model with the Pc space group in accordance with Mössbauer spectroscopy. The chemical composition was characterized by thermogravimetric analysis combined with mass spectroscopy, scanning transmission electron microscopy microanalysis and infrared spectroscopy. Nanosized cathode materials delivered electrochemical specific capacities of 130–134 mAh g−1 at 30 mA g−1 (C/5) in the 2.5–4.5 V (vs. K+/K) potential range. Diffusion coefficients determined by potentiostatic intermittent titration in a three-electrode cell reached 10−13 cm2 s−1 after full potassium extraction. It was shown that drying triggers no significant changes in crystal structure, iron oxidation state or electrochemical performance, though the water level clearly decreased from the pristine to air- and vacuum-dried samples.
Understanding the complex structural features and phase changes in Na 2 Mg 2 (SO 4 ) 3 : a combined single crystal and variable temperature powder diffraction and Raman spectroscopy study,
Lithium iron phosphate, LiFePO4, a widely used cathode
material in commercial Li-ion batteries, unveils a complex defect
structure, which is still being deciphered. Using a combined computational
and experimental approach comprising density functional theory (DFT)+U and molecular dynamics calculations and X-ray and neutron
diffraction, we provide a comprehensive characterization of various
OH point defects in LiFePO4, including their formation,
dynamics, and localization in the interstitial space and at Li, Fe,
and P sites. It is demonstrated that one, two, and four (five) OH
groups can effectively stabilize Li, Fe, and P vacancies, respectively.
The presence of D (H) at both Li and P sites for hydrothermally synthesized
deuterium-enriched LiFePO4 is confirmed by joint X-ray
and neutron powder diffraction structure refinement at 5 K that also
reveals a strong deficiency of P of 6%. The P occupancy decrease is
explained by the formation of hydrogarnet-like P/4H and P/5H defects,
which have the lowest formation energies among all considered OH defects.
Molecular dynamics simulation shows a rich structural diversity of
these defects, with OH groups pointing both inside and outside vacant
P tetrahedra creating numerous energetically close conformers, which
hinders their explicit localization with diffraction-based methods
solely. The discovered conformers include structural water molecules,
which are only by 0.04 eV/atom H higher in energy than separate OH
defects.
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