The photocatalytic removal of Flumequine (antibiotic) using a luminous textile which served as a support for the TiO 2 and a light transmitter through optical fibers was examined in this study. Two configurations of luminous textile were investigated (Mono-Face and Double-Face) in terms of compounds degradation and mineralization.Photocatalytic performances of Double-Face configuration were found to be better than the one obtained with Mono-Face. Furthermore, to describe the kinetics of the reaction, the Langmuir-Hinshelwood model was successfully applied and both reaction kinetic and adsorption/desorption equilibrium constants were determined. Double-Face configuration also showed better performances compared to the conventional process in the different 2 water matrices tested (ultrapure water, synthetic solution simulating seawater and synthetic hospital wastewater). This configuration was tested for cetirizine (antihistamine) degradation as well, with a satisfying result obtained. Moreover, this technology showed good stability and reusability. On the other hand, the larger size of Double-Face retained its performance at pilot-scale. Finally, the irradiation analyzes showed a good light distribution homogeneity on the textile surface at both laboratory-scale and pilot-scale.

International audienceDi (2-EthylHexyl) Phthalate (DEHP) was selected as a biodegradable organic solvent to be implemented in a two-phase partitioning bioreactor (TPPB) dedicated to remove a model hydrophobic volatile organic compound (VOC), toluene. In a first step, the absorption capacity of toluene in the selected organic solvent was examined according to the partition coefficients H. In a second step, toluene biodegradation in DEHP by non-acclimated activated sludge was carried out for different volume fractions of DEHP in water and five different toluene concentrations (4.3, 43, 106, 212 and 430 mg l−1). Toluene showed high affinity for DEHP with H = 0.99 Pa m3 mole−1. Both toluene and DEHP were completely consumed for 4.3 mg l−1 (initial toluene concentration) and a volume ratio of 0.1% DEHP in water. For an initial toluene concentration of 106 mg l−1 and a volume ratio of 0.1%, total toluene consumption and 87% DEHP degradation yield were obtained after seven days of incubation

A two-phase partitioning bioreactor was considered to remove toluene contained in a biodegradable organic phase by activated sludge (AS). The selected solvent was hexadecane. In a first step, the biodegradation of toluene dissolved in hexadecane by AS was examined. In a second step, acclimation of the AS was carried out in order to improve the biodegradation rate. Acclimation improved toluene removal, since biodegradation yield increased from 72% to more than 91%. A total consumption was observed after only 4 days culture with acclimated AS, since the rest of the toluene corresponded to gas leak; while in the case of non-acclimated sludge, losses cannot account for all non-degraded toluene. Regarding hexadecane, acclimation also improved its degradation, from 43% to 79% after 6 days culture for non-acclimated and acclimated AS, respectively.