Hybrid photonic integration exploits complementary strengths of different material platforms, thereby offering superior performance and design flexibility in comparison to monolithic approaches. This applies in particular to multi-chip concepts, where components can be individually optimized and tested on separate dies before integration into more complex systems. The assembly of such systems, however, still represents a major challenge, requiring complex and expensive processes for high-precision alignment as well as careful adaptation of optical mode profiles. Here we show that these challenges can be overcome by in-situ nano-printing of freeform beam-shaping elements to facets of optical components. The approach is applicable to a wide variety of devices and assembly concepts and allows adaptation of vastly dissimilar mode profiles while considerably relaxing alignment tolerances to the extent that scalable, cost-effective passive assembly techniques can be used. We experimentally prove the viability of the concept by fabricating and testing a selection of beam-shaping elements at chip and fiber facets, achieving coupling efficiencies of up to 88 % between an InP laser and an optical fiber. We also demonstrate printed freeform mirrors for simultaneously adapting beam shape and propagation direction, and we explore multi-lens systems for beam expansion. The concept paves the way to automated fabrication of photonic multi-chip assemblies with unprecedented performance and versatility.
Lithium-ion batteries are being increasingly used and deployed commercially. Cell-level improvements that address flammability characteristics and thermal runaway are currently being intensively tested and explored. In this study, three additives—namely, lithium oxalate, sodium fumarate and sodium malonate—which exhibit fire-retardant properties are investigated with respect to their incorporation into graphite anodes and their electro/chemical interactions within the anode and the cell material studied. It has been shown that flame-retardant concentrations of up to approximately 20 wt.% within the anode coating do not cause significant capacity degradation but can provide a flame-retardant effect due to their inherent, fire-retardant release of CO2 gas. The flame-retardant-containing layers exhibit good adhesion to the current collector. Their suitability in lithium-ion cells was tested in pouch cells and, when compared to pure graphite anodes, showed almost no deterioration regarding cell capacity when used in moderate (≤20 wt.%) concentrations.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.