Public concerns over potential environmental contamination associated with oil and gas well drilling and fracturing in the Wattenberg field in northeast Colorado are increasing. One of the issues of concern is the migration of oil, gas, or produced water to a groundwater aquifer resulting in contamination of drinking water. Since methane is the major component of natural gas and it can be dissolved and transported with groundwater, stray gas in aquifers has elicited attention. The initial step toward understanding the environmental impacts of oil and gas activities, such as well drilling and fracturing, is to determine the occurrence, where it is and where it came from. In this study, groundwater methane data that has been collected in response to a relatively new regulation in Colorado is analyzed. Dissolved methane was detected in 78% of groundwater wells with an average concentration of 4.0 mg/L and a range of 0-37.1 mg/L. Greater than 95% of the methane found in groundwater wells was classified as having a microbial origin, and there was minimal overlap between the C and H isotopic characterization of the produced gas and dissolved methane measured in the aquifer. Neither density of oil/gas wells nor distance to oil/gas wells had a significant impact on methane concentration suggesting other important factors were influencing methane generation and distribution. Thermogenic methane was detected in two aquifer wells indicating a potential contamination pathway from the producing formation, but microbial-origin gas was by far the predominant source of dissolved methane in the Wattenberg field.
Exploiting the energy of randomly moving active agents such as bacteria is a fascinating way to power a microdevice. Here we show, by simulations, that a chain-grafted disk-like colloidal particle can rotate unidirectionally and hence output work when immersed in a thin film of active particle suspension. The collective spontaneous symmetry breaking of chain configurations is the origin of the unidirectional rotation. Long persistence time, large propelling force and/or small rotating friction are keys to sustaining the collective broken symmetry and realizing the rotation. In the rotating state, we find very simple linear relations, e.g. between the mean angular speed and the propelling force. The time-evolving asymmetry of chain configurations reveals that there are two types of non-rotating state. The basic phenomena are also observed in the macroscopic granular experiments, implying the generic nature of these phenomena. Our findings provide new insights into the collective spontaneous symmetry breaking in active systems with flexible objects and also open the way to conceive new soft/deformable microdevices.
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