The technology of using metallic iron (Fe0) for in situ generation of iron oxides for water treatment is a very old one. The Fe0 remediation technology has been re-discovered in the framework of groundwater remediation using permeable reactive barriers (PRBs). Despite its simplicity, the improvement of Fe0 PRBs is fraught with difficulties regarding their operating modes. The literature dealing with Fe0 remediation contains ambiguities regarding its invention and its development. The present paper examines the sequence of contributions prior to the advent of Fe0 PRBs in order to clarify the seemingly complex picture. To achieve this, the current paper addresses the following questions: (i) What were the motivations of various authors in developing their respective innovations over the years?, (ii) what are the ancient achievements which can accelerate progress in knowledge for the development of Fe0 PRBs?, and (iii) was Fe0 really used for the removal of organic species for the first time in the 1970s? A careful examination of ancient works reveals that: (i) The wrong questions were asked during the past three decades, as Fe0 was premised as a reducing agent, (ii) credit for using Fe0 for water treatment belongs to no individual scientist, and (iii) credit for the use of Fe0 in filtration systems for safe drinking water provision belongs to scientists from the 1850s, while credit for the use of Fe0 for the removal of aqueous organic species does not belong to the pioneers of the Fe0 PRB technology. However, it was these pioneers who exploited Fe0 for groundwater remediation, thereby extending its potential. Complementing recent achievements with the chemistry of the Fe0/H2O system would facilitate the design of more sustainable Fe0-remediation systems.
Consumers consider various product attributes when they evaluate products. Researchers and practitioners have used multi-attribute models to understand which product attributes are important for consumers. However, in those models, product attributes are limited and are determined by researchers at the time of the inquiry. In this study, using a longitudinal study of hotel reviews over 6 years, the top 30 important hotel attributes from the perspective of consumers are identified and examined as to how the importance of these hotel attributes has changed over time. Our findings show that staff is the most important attribute with a positive effect on ratings at all times and that other attributes show consistent positive (negative) effects with small changes of importance over the years. Our study provides managerial implications of what attributes hotel managers need to maintain or improve for customer satisfaction.
The ambitious United Nations Sustainable Development Goal for 2030 to “leave no one behind” concerning safe drinking water calls for the development of universally applicable and affordable decentralized treatment systems to provide safe drinking water. Published results suggest that well-designed biological sand filters (BSFs) amended with metallic iron (Fe0-BSFs) have the potential to achieve this goal. Fe0-BSFs quantitatively remove pathogens and a myriad of chemical pollutants. The available data were achieved under various operating conditions. A comparison of independent research results is almost impossible, especially because the used Fe0 materials are not characterized for their intrinsic reactivity. This communication summarizes the state-of-the-art knowledge on designing Fe0-BSFs for households and small communities. The results show that significant research progress has been made on Fe0-BSFs. However, well-designed laboratory and field experiments are required to improve the available knowledge in order to develop the next generation of adaptable and scalable designs of Fe0-BSFs in only two years. Tools to alleviate the permeability loss, the preferential flow, and the use of exhausted filters are presented.
A critical survey of the abundant literature on environmental remediation and water treatment using metallic iron (Fe0) as reactive agent raises two major concerns: (i) the peculiar properties of the used materials are not properly considered and characterized, and, (ii) the literature review in individual publications is very selective, thereby excluding some fundamental principles. Fe0 specimens for water treatment are typically small in size. Before the advent of this technology and its application for environmental remediation, such small Fe0 particles have never been allowed to freely corrode for the long-term spanning several years. As concerning the selective literature review, the root cause is that Fe0 was considered as a (strong) reducing agent under environmental conditions. Subsequent interpretation of research results was mainly directed at supporting this mistaken view. The net result is that, within three decades, the Fe0 research community has developed itself to a sort of modern knowledge system. This communication is a further attempt to bring Fe0 research back to the highway of mainstream corrosion science, where the fundamentals of Fe0 technology are rooted. The inherent errors of selected approaches, currently considered as countermeasures to address the inherent limitations of the Fe0 technology are demonstrated. The misuse of the terms “reactivity”, and “efficiency”, and adsorption kinetics and isotherm models for Fe0 systems is also elucidated. The immense importance of Fe0/H2O systems in solving the long-lasting issue of universal safe drinking water provision and wastewater treatment calls for a science-based system design.
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