Keywords:MSW incineration fly ash Heavy metals Volatilization and leaching behavior DC arc plasma CaO -Al 2 O 3 -SiO 2 (CAS) A B S T R A C T Three fly ash samples collected from different waste incinerators were vitrified using a direct current arc plasma furnace at 1250-1400掳C. The influence of water-wash extraction and wrapping pretreatment on the volatilization and leaching behavior of heavy metals was investigated. Results showed: After thermal arc plasma treatment, the volume reduction and weight loss of fly ash were in the range of 68.7-82.2% and 23.8-56.7%, respectively. The residual fractions (wt.%) of heavy metals in slag are in the following sequence: Cr < Ni < Cd < Pb < Cu < Zn. Water-washing could reduce the volatilization rate of heavy metals due to some volatile salts removed by washing, while wrapping of fly ash could most effectively resist heavy metals against volatilizing, especially for Zn and Ni. The possible CaO -Al 2 O 3 -SiO 2 (CAS) ratio for successful melting of fly ash is suggested to be CaO in range of 20-48%, Al 2 O 3 in range of 10-15%, and SiO 2 in range of 40-65%. Moreover, toxicity characteristic leaching procedure results showed that the leaching of heavy metals in slags was much lower than the standard limit of toxicity characteristic leaching procedure (TCLP).
The influences of steady aerodynamic loads on hunting stability of high-speed railway vehicles were investigated in this study. A mechanism is suggested to explain the change of hunting behavior due to actions of aerodynamic loads: the aerodynamic loads can change the position of vehicle system (consequently the contact relations), the wheel/rail normal contact forces, the gravitational restoring forces/moments and the creep forces/moments. A mathematical model for hunting stability incorporating such influences was developed. A computer program capable of incorporating the effects of aerodynamic loads based on the model was written, and the critical speeds were calculated using this program. The dependences of linear and nonlinear critical speeds on suspension parameters considering aerodynamic loads were analyzed by using the orthogonal test method, the results were also compared with the situations without aerodynamic loads. It is shown that the most dominant factors affecting linear and nonlinear critical speeds are different whether the aerodynamic loads considered or not. The damping of yaw damper is the most dominant influencing factor for linear critical speeds, while the damping of lateral damper is most dominant for nonlinear ones. When the influences of aerodynamic loads are considered, the linear critical speeds decrease with the rise of cross wind velocity, whereas it is not the case for the nonlinear critical speeds. The variation trends of critical speeds with suspension parameters can be significantly changed by aerodynamic loads. Combined actions of aerodynamic loads and suspension parameters also affect the critical speeds. The effects of such joint action are more obvious for nonlinear critical speeds.
An internally circulating fluidized bed (ICFB) was applied to investigate the behavior of chlorine and sulfur during cofiring RDF and coal. The pollutant emissions in the flue gas were measured by Fourier transform infrared (FTIR) spectrometry (Gasmet DX-3000). In the tests, the concentrations of the species CO, CO 2 , HCl, and SO 2 were measured online. Results indicated when cofiring RDF and char, due to the higher content of chlorine in RDF, the formation of HCl significantly increases. The concentration of SO 2 is relatively low because alkaline metal in the fuel ash can absorb SO 2 . The concentration of CO emission during firing pure RDF is relatively higher and fluctuates sharply. With the CaO addition, the sulfur absorption by calcium quickly increases, and the desulfuration ratio is bigger than the dechlorination ratio. The chemical equilibrium method is applied to predict the behavior of chlorine. Results show that gaseous HCl emission increases with increasing RDF fraction, and gaseous KCl and NaCl formation might occur.
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