An ultra-thin, stretchable, and transparent hydrogenbonded poly(ethylene oxide) and poly(acrylic acid) ([PEO/PAA] n ) bilayer (BL) positive triboelectric film was developed using a low-cost and eco-friendly layer-by-layer method. [PEO/PAA] n films exhibited remarkable output performance, enabling designability, foldability, and sustainability for versatile application of triboelectric nanogenerators (TENGs). The dependence of TENG behaviors on thickness was investigated by varying the number of BLs in [PEO/PAA] n films. It was demonstrated that a 1.6-μm-thick [PEO/PAA] 20 TENG resulted in an optimal electrical output performance of 303 V and 36.1 mA m −2 , owing to a higher affinity for electron donation and the lowest work function. A free-standing (FS) skin-like [PEO/PAA] 100 TENG was designed for shape-adaptive kirigami-type nanogenerators, exhibiting ∼100% ultrahigh transparency, ∼900% super-stretchability, and extraordinary foldability to 1/32 its original size. Thus, FS-TENG could be attached to the skin, a wall, or the insole of a shoe, showing an output of 321, 501, and 319 V, respectively, enough to simultaneously turn on 39 green LEDs by manually tapping or running.
Serious climate changes and energy-related environmental
problems
are currently critical issues in the world. In order to reduce carbon
emissions and save our environment, renewable energy harvesting technologies
will serve as a key solution in the near future. Among them, triboelectric
nanogenerators (TENGs), which is one of the most promising mechanical
energy harvesters by means of contact electrification phenomenon,
are explosively developing due to abundant wasting mechanical energy
sources and a number of superior advantages in a wide availability
and selection of materials, relatively simple device configurations,
and low-cost processing. Significant experimental and theoretical
efforts have been achieved toward understanding fundamental behaviors
and a wide range of demonstrations since its report in 2012. As a
result, considerable technological advancement has been exhibited
and it advances the timeline of achievement in the proposed roadmap.
Now, the technology has reached the stage of prototype development
with verification of performance beyond the lab scale environment
toward its commercialization. In this review, distinguished authors
in the world worked together to summarize the state of the art in
theory, materials, devices, systems, circuits, and applications in
TENG fields. The great research achievements of researchers in this
field around the world over the past decade are expected to play a
major role in coming to fruition of unexpectedly accelerated technological
advances over the next decade.
Recently, triboelectric nanogenerators (TENGs) have been widely utilized to address the energy demand of portable electronic devices by harvesting electrical energy from human activities or immediate surroundings. To increase the surface charge and surface area of negative TENGs, previous studies suggested several approaches such as micro-patterned arrays, porous structures, multilayer alignment, ion injections, ground systems and mixing of high dielectric constant materials. However, the preparation processes of these nanocomposite TENGs have been found to be complex and expensive. In this work, we report a simple, efficient and inexpensive modification of poly(dimethylsiloxane) (PDMS) using graphene nanoplatelets (GNPs) fillers and a Na2CO3 template. This GNP-PDMS was chemically bonded using 3-aminopropylethoxysilane (APTES) as a linker with an electrode multilayer made by layer-by-layer deposition of polyvinyl alcohol (PVA) and poly(4-styrene-sulfonic acid) (PSS)-stabilized GNP (denoted as [PVA/GNP-PSS]n). A 33 wt.% Na2CO3 and 0.5 wt.% of GNP into a PDMS-based TENG gives an open-circuit voltage and short-circuit current density of up to ~270.2 V and ~0.44 μA/cm2, which are ~8.7 and ~3.5 times higher than those of the pristine PDMS, respectively. The higher output performance is due to (1) the improved surface charge density, 54.49 μC/m2, from oxygen functional moieties of GNP, (2) high surface roughness of the composite film, ~0.399 μm, which also increased the effective contact area, and (3) reduced charge leakage from chemical bonding of GNP-PDMS and [PVA/GNP-PSS]3 via APTES. The proposed TENG fabrication process could be useful for the development of other high-performance TENGs.
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