The compound (CsHTOz)3Ru crystallizes in the monoclinic space group P2,/e, with a= 13"86 (1), b= 7.53 (1), c= 16.01 (4) ~, and fl= 99.10 (1) °. The central ruthenium atom is surrounded octahedrally by six oxygen atoms. The average Ru-O distance is 2.00 A,. The crystal is isomorphous with the trisacetylacetonato complexes of AI, Co, Cr, Mn and Rh.
Key indicators: single-crystal X-ray study; T = 296 K; mean (C-C) = 0.003 Å; R factor = 0.031; wR factor = 0.078; data-to-parameter ratio = 23.9.The title complex salt, (C 8 H 20
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Key indicators: single-crystal X-ray study; T = 296 K; mean (C-C) = 0.006 Å; R factor = 0.032; wR factor = 0.083; data-to-parameter ratio = 23.4.In the title complex, [Ru(C 6 H 14 O 2 PS 2 ) 3 ], the coordination environment of the Ru III atom is distorted octahedral, defined by six S atoms from three S,S 0 -bidentate diisopropyl dithiophosphate ligands. The average Ru-S bond length is 2.41 (1) Å and the average S-Ru-S bite angle is 81.13 (19) .
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ExperimentalCrystal data
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