The breakdown of O,O-diethyl-2,4-dinitrophenyl phosphate (DEDNPP) in formamide (FMD) solutions is assessed using kinetic studies and 31P nuclear magnetic resonance (NMR). Regiospecific nucleophilic amidolysis via P–O bond cleavage is observed,...
The competitive formation of isomeric bridged lactams via acid-catalyzed intramolecular Schmidt reactions from 3-azidoethylcyclopentanones is explored using density functional theory (DFT) calculations, primarily performed at M06-2X/6-311++G(d,p) level of theory. Results...
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