Manipulation of the emission properties of pure organic room-temperature phosphors through molecular design is attractive but challenging. Tremendous efforts have been made to modulate their aggregation behaviors to suppress nonradiative decay in order to achieve efficient light emission and long lifetimes. However, success has been limited. To attain such a goal, here we present a rational design principle based on intrinsic molecular-structure engineering. Comprehensive investigations on the molecular orbitals revealed that an excited state with hybrid (n,p*) and (p,p*) configurations in appreciable proportion is desired. Tailoring the aromatic subunits in arylphenones can effectively tune the energy level and the orbital feature of the triplet exciton. Our experimental data reveal that a series of full-color pure organic phosphors with a balanced lifetime (up to 0.23 s) and efficiency (up to 36.0%) can be realized under ambient conditions, demonstrating the validity of our instructive design principle.
Material that can emit broad spectral wavelengths covering deep ultraviolet, visible, and near-infrared is highly desirable. It can lead to important applications such as broadband modulators, photodetectors, solar cells, bioimaging, and fiber communications. However, there is currently no material that meets such desirable requirement. Here, we report the layered structure of nitrogen-doped graphene quantum dots (N-GQDs) which possess broadband emission ranging from 300 to >1000 nm. The broadband emission is attributed to the layered structure of the N-GQDs that contains a large conjugated system and provides extensive delocalized π electrons. In addition, a broadband photodetector with responsivity as high as 325 V/W is demonstrated by coating N-GQDs onto interdigital gold electrodes. The unusual negative photocurrent is observed which is attributed to the trapping sites induced by the self-passivated surface states in the N-GQDs.
Organic luminescent materials carrying
no phenyl rings have attracted
much interest from researchers due to their excellent biocompatibility
and good biodegradability, which make them available for potential
applications in a variety of biomedical areas, such as fluorescent
bioprobe, drug delivery and gene carrier, and provide a new insight
into the photophysical process of light emission. In this work, we
studied the optical properties of poly[(maleic anhydride)-alt-(vinyl acetate)] (PMV), a pure oxygenic nonconjugated
polymer and proved that the origin of its emission was associated
with the clustering of the locked carbonyl groups. PMV exhibits solvatochromism:
after interaction with electron-rich solvents, its absorption and
emission shift to the longer wavelength region due to the formation
of polymer/solvent complexes. This enables fine-tuning of its optical
property by varying the solvent without the need of changing the chromophore.
Upconversion luminescence (UCL) refers to nonlinear optical processes, which can convert near-infrared photons to short-wavelength emission. Recent advances in nanotechnology have contributed to the development of photon upconversion materials as promising new generation candidates of fluorescent bioprobes and spectral converters for biomedical and optoelectronic applications. Apart from the remarkable photoluminescence of the materials under photon excitation, some UCL materials may exhibit intrinsic magnetic, ferroelectric, X-ray absorption properties, and so on. These interesting characteristics provide an opportunity for us to couple a single stimulus or multiple stimuli (electric field, magnetic field, X-ray, electron beam, temperature and pH, etc.) to various types of UCL materials. In this review, we will primarily focus on the stimuli responsive properties of UCL materials beyond light-matter interaction, which can aid both fundamental research and widespread applications of the materials. The mechanisms of the response to various stimuli in the UCL materials are discussed. This article will also highlight recent advances in the development of these materials in response to various stimuli and their applications in multimodal bioimaging, drug delivery and release, electro-optical devices, magnetic, temperature and pH sensors and multiple anti-counterfeiting inks. Lastly, we will present potential directions of future research and challenging issues which arise in expanding the applications of stimuli responsive UCL materials.
A 2D system of Er-doped MoS2 layered nanosheets is developed. Structural studies indicate that the Er atoms can be substitutionally introduced into MoS2 to form stable doping. Density functional theory calculation implies that the system remains stable. Both NIR-to-NIR up-conversion and down-conversion light-emissions are observed in 2D transition metal dichalcogenides, ascribed to the energy transition from Er(3+) dopants.
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