Kamihara and coworkers' report of superconductivity at T c ¼ 26 K in fluorine-doped LaFeAsO inspired a worldwide effort to understand the nature of the superconductivity in this new class of compounds. These iron pnictide and chalcogenide (FePn/Ch) superconductors have Fe electrons at the Fermi surface, plus an unusual Fermiology that can change rapidly with doping, which lead to normal and superconducting state properties very different from those in standard electron-phonon coupled ''conventional'' superconductors. Clearly, superconductivity and magnetism or magnetic fluctuations are intimately related in the FePn/Ch, and even coexist in some. Open questions, including the superconducting nodal structure in a number of compounds, abound and are often dependent on improved sample quality for their solution. With T c values up to 56 K, the six distinct Fe-containing superconducting structures exhibit complex but often comparable behaviors. The search for correlations and explanations in this fascinating field of research would benefit from an organization of the large, seemingly disparate data set. This review provides an overview, using numerous references, with a focus on the materials and their superconductivity.
Carbon isotope natural abundance (δ13C) has been previously used as a powerful tool in the study of water-using processes at the leaf, individual and within-community levels. We analysed 348 species from 12 plant communities along a 900 km-long rainfall gradient in southern Queensland. Although the range of δ13C values found in a given community was large, variability in the δ13C signature of plants within a community was relatively small given the large numbers of species sampled (mean n per site of 29) and the taxonomic diversity in each. The community-averaged δ13C signature ranged from -25.60 in a brigalow (Acacia harpophylla) dominated community in western Queensland to - 31.20 in subtropical rainforest in eastern Queensland. A strong relationship was found between the δ13C value averaged for each site and rainfall within the range 350-1700 mm per annum. Foliar δ13C was also related to the number of rain days per annum and moisture balance (rainfall - evaporation). The strength of these relationships varied only slightly according to the rainfall parameter used, with values for r2 of 0.78, 0.70, 0.70 and 0.74 for the relationship between δ13C and long-term rainfall average, 5-year rainfall average, number of rain days and moisture balance, respectively. Despite considerable taxonomic variability within a given plant community, the averaged δ13C signature for that community gives a strong indication of moisture availability.
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