Damage is a key problem that limits the application of polymer membranes. In this paper, conductive carbon black (CB) and silicon dioxide (SiO2)-reinforced polyvinylidene fluoride (PVDF) composites were prepared using a solution mixing method. Through a uniaxial tensile test, the fracture and damage characteristics of the material were analyzed. When the structure had inevitable notch damage, changing the notch angle was very helpful for the material to bear more load. In addition, when there were two kinds of fillers in the PVDF matrix at the same time, there was an interaction between particles. The microstructure of the composite was characterized by scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), and thermogravimetric (TG) analysis. The experimental results indicate that, when the ratio of CB:SiO2:PVDF was 1:4:95, the general mechanical properties of the composite were the best.
In this paper, solution casting method is used to prepare the PP (polypropylene) non-woven fabric based composite film filled with silicon dioxide/polyvinylidene fluoride (SiO2/PVDF). The mechanical and thermodynamic properties of PP/SiO2/PVDF composites were studied by a uniaxial tensile test under different temperature and combustion experiment. It is found that the stress of PP/SiO2/PVDF composite film with 4 wt % SiO2 is the maximum value, reaching 18.314 MPa, 244.42% higher than that of pure PP non-woven. Meanwhile, the thermal–mechanical coupling tests indicate that with the increase of temperature, the ultimate stress and strain of the composite decrease. At the same time, the thermal shrinkage property of the composite during the heating process is studied. The modified composite has good thermal stability under 180 °C. Scanning electron microscope (SEM), X-ray diffraction (XRD) and thermogravimetric (TG) were used to characterize the pore shape, distribution and crystal phase change of the composite. The modified PP/SiO2/PVDF composite film structure shows high strength and good thermal stability, and can better meet the requirements of strength and thermal performance of lithium-ion battery during the charging and discharging process.
Structural vibration induced by dynamic load or natural vibration is a non-negligible factor in failure analysis. Based on a vibrating boundary condition, the impact resistance of shape memory alloy (SMA)-reinforced composites was investigated. In this investigation, a modified Hashin’s failure criterion, Brinson’s model, and a visco-hyperelastic model were implemented into a numerical model to characterize the mechanical behavior of glass fiber/epoxy resin laminates, SMAs, and interphase, respectively. First, a fixed boundary condition was maintained in the simulation to verify the accuracy of the material parameters and procedures by a comparison with experimental data. Then, a series of vibrating boundaries with different frequencies and amplitudes was applied during the simulation process to reveal the effect on impact resistances. The results indicate that the impact resistance of the composite under a higher frequency or a larger amplitude is lower than that under a lower frequency or a smaller amplitude.
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