In organic solar cells, the resulting device efficiency depends strongly on the local morphology and intermolecular interactions of the blend film. Optical spectroscopy was used to identify the spectral signatures of interacting chromophores in blend films of the donor polymer PM6 with two state‐of‐the‐art nonfullerene acceptors, Y6 and N4, which differ merely in the branching point of the side chain. From temperature‐dependent absorption and luminescence spectroscopy in solution, it is inferred that both acceptor materials form two types of aggregates that differ in their interaction energy. Y6 forms an aggregate with a predominant J‐type character in solution, while for N4 molecules the interaction is predominantly in a H‐like manner in solution and freshly spin‐cast film, yet the molecules reorient with respect to each other with time or thermal annealing to adopt a more J‐type interaction. The different aggregation behavior of the acceptor materials is also reflected in the blend films and accounts for the different solar cell efficiencies reported with the two blends.
The development of an environmentally friendly fabrication process for non-fullerene acceptor organic solar cells is an essential condition for their commercialization. However, devices fabricated by processing the active layer with...
Polymeric thin films offer a wide range of exciting properties and applications, with several advantages compared to inorganic counterparts. The thermal conductivity of such thin films ranges typically between 0.1–1 W m−1 K−1. This low thermal conductivity can cause problems with heat dissipation in various applications. Detailed knowledge about thermal transport in polymeric thin films is desired to overcome these shortcomings, especially in light of the multitude of possible microstructures for semi-crystalline thin films. Therefore, poly(3-hexylthiophene-2,5-diyl) (P3HT) is chosen as a model system to analyze the microstructure and optoelectronic properties using X-ray scattering and absorption spectra along with the thermal transport properties using the photoacoustic technique. This combination of analysis methods allows for determining the optoelectronic and thermal transport properties on the same specimen, supplemented by structural information. The effect of different molecular weights and solvents during film preparation is systematically examined. A variation of the optoelectronic properties, mainly regarding molecular weight, is apparent, while no direct influence of the solvent during preparation is discernible. In contrast, the thermal conductivities of all films examined fall within a similar range. Therefore, the microstructural properties in the ordered regions do not significantly affect the resulting thermal properties in the sample space investigated in this work. We conclude that it is mainly the amorphous regions that determine the thermal transport properties, as these represent a bottleneck for thermal transport.
A major advantage of organic solar
cells (OSC) is the processability out of solution allowing for advanced
printing methods toward large-scale production. Controlling the blend
morphology of solution coated active layers is a key challenge to
optimize their power conversion efficiency. We have derived a printing
procedure from an industrial coating process that facilitates tuning
the nanomorphology of a blend of poly(3-hexylthiophene) (P3HT) and
[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as model system
for OSCs. Applying an electric field during printing and the film
drying process modifies the vertical film composition of the photoactive
layer and optimizes the polymer crystal orientation. The choice of
chloroform as solvent allows us to obtain material transport within
the wet film, due to an induced electrophoretic mobility. Tailoring
the morphology improves the power conversion efficiency of the OSCs
by up to 25%. Our findings indicate that electrophoresis assisted
printing provides an efficient approach to optimize the active layer
for various material and solvent combinations that exhibit an electrophoretic
mobility.
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