We, for the first time, provide the experimental demonstration on the band gap engineering of layered hexagonal SnSe2 nanostructured thin films by varying the thickness. For 50 nm thick film, the band gap is ~2.04 eV similar to that of monolayer, whereas the band gap is approximately ~1.2 eV similar to that of bulk for the 1200 nm thick film. The variation of the band gap is consistent with the the theoretically predicted layer-dependent band gap of SnSe2. Interestingly, the 400–1200 nm thick films were sensitiveto 1064 nm laser iradiation and the sensitivity increases almost exponentiallly with thickness, while films with 50–140 nm thick are insensitive which is due to the fact that the band gap of thinner films is greater than the energy corresponding to 1064 nm. Over all, our results establish the possibility of engineering the band gap of SnSe2 layered structures by simply controlling the thickness of the film to absorb a wide range of electromagnetic radiation from infra-red to visible range.
In photodetection, the response time
is mainly controlled by the
device architecture and electron/hole mobility, while the absorption
coefficient and the effective separation of the electrons/holes are
the key parameters for high responsivity. Here, we report an approach
toward the fast and highly responsive infrared photodetection using
an n-type SnSe2 thin film on a p-Si(100) substrate keeping
the overall performance of the device. The I–V characteristics of the device show a rectification ratio
of ∼147 at ±5 V and enhanced optoelectronic properties
under 1064 nm radiation. The responsivity is 0.12 A/W at 5 V, and
the response/recovery time constants were estimated as ∼57
± 25/34 ± 15 μs, respectively. Overall, the response
times are shown to be controlled by the mobility of the constituent
semiconductors of a photodiode. Further, our findings suggest that
n-SnSe2 can be integrated with well-established Si technology
with enhanced optoelectronic properties and also pave the way in the
design of fast response photodetectors for other wavelengths as well.
An extrinsic approach toward achieving fast response and self‐powered photodetector is reported. It is shown that an organic–inorganic hybrid device (SnSe2/PEDOT:PSS) not only operates in self‐powered mode for infra‐red photodetection but also improves the response time with respect to inorganic (SnSe2) linear devices. Fast response and recovery time constants of ≈1.33 and 1.22 s, respectively, are obtained. Furthermore, the sensitivity is highest at zero bias and the device is stable for over 6 months stored in open air condition. The observed photo‐current, faster response and recovery time constants are ascribed to the formation of a strong built‐in electric field at the interface between SnSe2 and PEDOT:PSS. In a broader view of these findings, the device proves its potential as a self‐powered photo‐detector and the results reported here can pave the way to design self‐powered and fast response for other wavelengths.
We report detailed structural, electrical transport and IR photoresponse properties of large area VO2(M1) thin films deposited by a simple cost-effective two-step technique.
While band gap and absorption coefficients are intrinsic properties of a material and determine its spectral range, response time is mainly controlled by the architecture of the device and electron/hole mobility. Further, 2D-layered materials such as transition metal dichalogenides (TMDCs) possess inherent and intriguing properties such as a layer-dependent band gap and are envisaged as alternative materials to replace conventional silicon (Si) and indium gallium arsenide (InGaAs) infrared photodetectors. The most researched 2D material is graphene with a response time between 50 and 100 ps and a responsivity of <10 mA/W across all wavelengths. Conventional Si photodiodes have a response time of about 50 ps with maximum responsivity of about 500 mA/W at 880 nm. Although the responsivity of TMDCs can reach beyond 104 A/W, response times fall short by 3–6 orders of magnitude compared to graphene, commercial Si, and InGaAs photodiodes. Slow response times limit their application in devices requiring high frequency. Here, we highlight some of the recent developments made with visible and near-infrared photodetectors based on two dimensional SnSe2 and MoS2 materials and their performance with the main emphasis on the role played by the mobility of the constituency semiconductors to response/recovery times associated with the hetero-structures.
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