Heterostructure
formation is an effective method used for designing
photocatalysts that solve problems caused by photoexcited charge recombination
phenomena associated with the photocatalytic water redox reaction.
This work reports a new Co-metal-incorporated ternary heterostructured
photocatalyst, CdS/CoO
x
/Co-metal, which
enhanced charge separation to increase photocatalytic H2 evolution 30.5-fold in comparison to pure CdS under visible light.
This work demonstrates for the first time the effect of the Co metal
on photocatalytic H2 evolution using the CdS/CoO
x
/Co-metal ternary heterostructure. In the ternary
heterostructure, Co metal and CoO
x
act
as photogenerated electron- and hole-capturing cocatalysts, respectively.
Results from photoelectrochemical studies along with photocatalytic
H2 evolution data proved the enhancement of charge transfer
and separation in the CdS/CoO
x
/Co-metal
heterostructure due to the addition of Co metal and CoO
x
. Hence, the synergistic charge separation improvement
achieved by the combination of CoO
x
and
the Co metal with CdS produced a photocatalytic H2 evolution
rate of 9.54 μmol/h, which is the highest reported H2 evolution rate for a CdS-based system under l sun solar irradiance
(>420 nm) to the best of our knowledge.
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