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[1] Total CO 2 output from fumaroles, soil gas, bubbling gas discharges and water dissolved gases discharged from the island, was estimated for Vulcano island, Italy. The CO 2 emission from fumaroles from the La Fossa summit crater was estimated from the SO 2 crater output, while CO 2 discharged through diffuse soil emission was quantified on the basis of 730 measurements of CO 2 fluxes from the soil of the island, performed by using the accumulation chamber method. The results indicate an overall output of ≅500 t day À1 of CO 2 from the island. The main contribution to the total CO 2 output comes from the summit area of the La Fossa cone (453 t day À1 ), with 362 t day À1 from crater fumaroles and 91 t day À1 from crater soil degassing. The release of CO 2 from peripheral areas is ≅20 t day À1 by soil degassing (Palizzi and Istmo areas mainly), an amount comparable to both the contribution of water dissolved CO 2 (6 t day À1 ), as well as to seawater bubbling CO 2 (4 t day À1 measured in the Istmo area). Presented data (September 2007) refer to a period of moderate solphataric activity, when the fumaroles temperature were 450°C and gas/water molar ratio of fumaroles was up to 0.16. The calculated total CO 2 emission allows the estimation of the mass release and related thermal energy from the volcanic-hydrothermal system.

Earth degassing of CO2-rich fluids has been proven to contribute significantly to the global carbon budget. The presence of ubiquitous outgassing reveals some degree of permeability of the crust that often coincides with seismically active zones. In this study, we took advantage of the most recent global geological datasets to better understand earth degassing and how it correlates with tectonic regimes. Here we use an ad hoc point pattern analysis to show that there is a spatial correlation between CO2 discharges and the presence of active fault systems, in particular with those characterized by a normal slip type. Seismic data demonstrate the existence of a positive spatial correlation between gas discharges and extensional tectonic regimes and confirms that such processes would play a key role in creating pathways for the rising gases at micro- and macro-scales, increasing the rock permeability and connecting the deep crust to the earth surface.

Eruption forecasting is a major goal in volcanology. Logically, but unfortunately, forecasting hazards related to non-magmatic unrest is too often overshadowed by eruption forecasting, although many volcanoes often pass through states of non-eruptive and non-magmatic unrest for various and prolonged periods of time. Volcanic hazards related to non-magmatic unrest can be highly violent and/or destructive (e.g., phreatic eruptions, secondary lahars), can lead into magmatic and eventually eruptive unrest, and can be more difficult to forecast than magmatic unrest, for various reasons. The duration of a state of non-magmatic unrest and the cause, type and locus of hazardous events can be highly variable. Moreover, non-magmatic hazards can be related to factors external to the volcano (e.g., climate, earthquake). So far, monitoring networks are often limited to the usual seismic-ground deformation-gas network, whereas recognizing indicators for non-magmatic unrest requires additional approaches. In this study we summarize non-magmatic unrest processes and potential indicators for related hazards. We propose an event-tree to classify non-magmatic unrest, which aims to cover all major hazardous outcomes. This structure could become useful for future probabilistic non-magmatic hazard assessments, and might reveal clues for future monitoring strategies.

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