Developing cheap and stable membrane electrode assembly for proton exchange membrane water electrolysis (PEMWE) plays critical roles in renewable energy revolution. Iridium is the commonly efficient oxygen evolution reaction catalyst. But the reserve in earth is a shortage. Herein, an ordered array electrode in feature of the defective Ir film decorated on external WO x nanorods (WO x NRs) is designed. Electrodeposition is carried out to prepare an iridium coating (∼68 nm in thickness) to guarantee the ordered morphology. This novel electrode obtained brilliant I−V performances (2.2 A cm −2 @2.0 V) and 1030 h stability (0.5 mA cm −2 ) with a reduced loading of 0.14 mg Ir cm −2 . The uniform dispersion Ir catalyst on the WO x substrate benefits to enhance Ir mass activity and improve the poor conductivity originating from WO x . Compared with that of sprayed electrode, the threshold current density of mass transport polarization region can be expande to at least 3.0 A cm −2 for ordered structure electrode attributed to the abundant water storage bulk. This novel Ir@WO x NRs electrode occupies a huge potential to defuse the cost and durability issues confronting with the PEMWE.

Developing highly active and stable HOR catalysts still remains a challenging task for alkaline anion exchange membrane fuel cells.