Employing carbonyl iron powder and Ethylene-Propylene-Diene Monomer (EPDM) as the absorbent and matrix, rubber radar absorbing materials (RAM) were prepared. Effects of the carbonyl iron volume fraction and the thickness of the RAM on the microwave absorption properties in the frequency range of 2.6-18GHz were studied, and a mathematical analysis was made using the electromagnetic theory. The experimental results indicate that the minimum refl ectivity of the radar absorbing materials continuously decreases with the increase of the carbonyl iron volume fraction, and the absorption peak also moves towards the low frequency for the same thickness of the RAM. The minimum reflectivity of the 3.0 mm RAM is -21.7dB at 3.5 GHz when the volume fraction of carbonyl iron is 45%. The reflectivity of the RAM is not in direct proportional to the thickness of the RAM, when the RAM has the same volume fraction of the carbonyl iron. The refl ectivity of the RAM presents a regular trend at a given carbonyl iron volume fraction in the frequency range of 2.6-18 GHz. With the increase of the thickness, the maximum absorption peak moves towards low frequency band, the minimum reflectivity firstly decreases and then increases, and the absorption bandwidth for refl ectivity<-10 dB fi rstly increases and then decreases. The microwave absorption properties of the RAM are determined by the thickness and the composition of the radar absorbing materials. Theoretical analysis indicates that the refl ectivity of the RAM is determined by the matching degree of the air's characteristic impedance and the input impedance.
In this work, a series of TATB‐based aluminized explosives were formulated from 1, 3, 5‐triamino‐2, 4, 6‐trinitrobenzene (TATB), aluminum powders and polymeric binders. The thermal stability, heat of detonation, detonation velocity and pressure of the TATB based aluminized (TATB/Al) explosives were systematically investigated by cook‐off, constant temperature calorimeter, electrometric method and manganin piezo resistance gauge, respectively. The selected PBX‐3 (70 wt% TATB/25 wt% Al/5 wt% fluorine resin) achieved optimized balance between thermal stability and detonation performance, with the thermal runaway temperature around 583 K. The thermal ignition of TATB‐based aluminized explosive occurred at the edge of the cylinder according to the experimental and numerical simulations. Moreover, the critical thermal runaway temperature for PBX‐3 was calculated based on the Semenov's thermal explosion theory and the thermal decomposition kinetic parameters of the explosive, which was consistent with the experimental value.
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